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The Chemistry of the Actinide and Transactinide Elements Third Edition +/- redox complexation desorption sorption dissolution precipitation Edited by Lester R. Morss, Norman M. Edelstein & Jean Fuger THE CHEMISTRY OF THE ACTINIDE AND TRANSACTINIDE ELEMENTS Joseph J. Katz Glenn T. Seaborg This work is dedicated to Joseph J. Katz and Glenn T. Seaborg, authors of the first and second editions of The Chemistry of the Actinide Elements and leaders in the field of actinide chemistry. THE CHEMISTRY OF THE ACTINIDE AND TRANSACTINIDE ELEMENTS THIRD EDITION Volume 1 EDITED BY Lester R. Morss ArgonneNationalLaboratory, Argonne,Illinois,USA Norman M. Edelstein LawrenceBerkeleyNationalLaboratory, Berkeley,California,USA Jean Fuger UniversityofLie`ge, Lie`ge,Belgium Honorary Editor Joseph J. Katz ArgonneNationalLaboratory LibraryofCongressControlNumber:2008922620 ISBN-101-4020-3555-1(HB) ISBN-101-4020-3598-5(e-book) ISBN-13978-1-4020-3555-5(HB) ISBN-13978-1-4020-3598-2(e-book) PublishedbySpringer, P.O.Box17,3300AADordrecht,TheNetherlands. www.springer.com Printedonacid-freepaper AllRightsReserved Firstpublishedin2006 Reprinted2006 Reprintedwithcorrectionsin2008 #2006and2008SpringerScience+BusinessMediaB.V. Nopartofthisworkmaybereproduced,storedinaretrievalsystem,ortransmitted inanyformorbyanymeans,electronic,mechanical,photocopying,microfilming,recording orotherwise,withoutwrittenpermissionfromthePublisher,withtheexception ofanymaterialsuppliedspecificallyforthepurposeofbeingentered andexecutedonacomputersystem,forexclusiveusebythepurchaserofthework. CONTENTS Volume 1 Contributors ix Preface xv 1. Introduction 1 JosephJ.Katz,LesterR.Morss,NormanM.Edelstein, andJeanFuger 2. Actinium 18 H.W.KirbyandL.R.Morss 3. Thorium 52 MathiasS.Wickleder,BlandineFourest,andPeterK.Dorhout 4. Protactinium 161 BorisF.Myasoedov,H.W.Kirby,andIvanG.Tananaev 5. Uranium 253 IngmarGrenthe,JanuszDroz˙dz˙yn´ski,TakeoFujino, EdgarC.Buck,ThomasE.Albrecht-Schmitt,andStephenF.Wolf SubjectIndex(Volume1) I-1 AuthorIndex(Volume1) I-31 Volume 2 Contributors ix Preface xv 6. Neptunium 699 ZenkoYoshida,StephenG.Johnson,TakaumiKimura,and JohnR.Krsul 7. Plutonium 813 DavidL.Clark,SiegfriedS.Hecker,GordonD.Jarvinen,and MaryP.Neu 8. Americium 1265 WolfgangH.RundeandWallaceW.Schulz SubjectIndex(Volume2) I-1 AuthorIndex(Volume2) I-27 v vi Contents Volume 3 Contributors ix Preface xv 9. Curium 1397 GreggJ.Lumetta,MajorC.Thompson, RobertA.Penneman,andP.GaryEller 10. Berkelium 1444 DavidE.HobartandJosephR.Peterson 11. Californium 1499 RichardG.Haire 12. Einsteinium 1577 RichardG.Haire 13. Fermium,Mendelevium,Nobelium,andLawrencium 1621 RobertJ.Silva 14. TransactinideElementsandFutureElements 1652 DarleaneC.Hoffman,DianaM.Lee,andValeriaPershina 15. SummaryandComparisonofPropertiesoftheActinideand TransactinideElements 1753 NormanM.Edelstein,JeanFuger,JosephJ.Katz,and LesterR.Morss 16. SpectraandElectronicStructuresofFreeActinide AtomsandIons 1836 EarlF.Worden,JeanBlaise,MarkFred,NorbertTrautmann, andJean-Franc¸oisWyart 17. TheoreticalStudiesoftheElectronicStructureofCompounds oftheActinideElements 1893 NikolasKaltsoyannis,P.JeffreyHay,JunLi,Jean-PhilippeBlaudeau, andBruceE.Bursten 18. OpticalSpectraandElectronicStructure 2013 GuokuiLiuandJamesV.Beitz SubjectIndex(Volume3) I-1 AuthorIndex(Volume3) I-39 Volume 4 Contributors ix Preface xv 19. ThermodynamicPropertiesofActinidesandActinideCompounds 2113 RudyJ.M.Konings,LesterR.Morss,andJeanFuger 20. MagneticProperties 2225 NormanM.EdelsteinandGerardH.Lander Contents vii 21. 5f-ElectronPhenomenaintheMetallicState 2307 A.J.Arko,JohnJ.Joyce,andLadiaHavela 22. ActinideStructuralChemistry 2380 KeithE.Gutowski,NicholasJ.Bridges,andRobinD.Rogers 23. ActinidesinSolution:ComplexationandKinetics 2524 GregoryR.ChoppinandMarkP.Jensen 24. ActinideSeparationScienceandTechnology 2622 KennethL.Nash,CharlesMadic,JagdishN.Mathur, andJe´roˆmeLacquement SubjectIndex(Volume4) I-1 AuthorIndex(Volume4) I-35 Volume 5 Contributors ix Preface xv 25. OrganoactinideChemistry:SynthesisandCharacterization 2799 CarolJ.BurnsandMorisS.Eisen 26. HomogeneousandHeterogeneousCatalyticProcesses PromotedbyOrganoactinides 2911 CarolJ.BurnsandMorisS.Eisen 27. IdentificationandSpeciationofActinidesintheEnvironment 3013 ClaudeDegueldre 28. X-rayAbsorptionSpectroscopyoftheActinides 3086 MarkR.AntonioandLyndaSoderholm 29. Handling,Storage,andDispositionofPlutoniumandUranium 3199 JohnM.HaschkeandJerryL.Stakebake 30. TraceAnalysisofActinidesinGeological,Environmental, andBiologicalMatrices 3273 StephenF.Wolf 31. ActinidesinAnimalsandMan 3339 PatriciaW.Durbin AppendixI NuclearSpinsandMomentsoftheActinides 3441 IrshadAhmad AppendixII NuclearPropertiesofActinideandTransactinideNuclides 3442 IrshadAhmad CumulativeSubjectIndex(Volumes1,2,3,4and5) I-1 CumulativeAuthorIndex(Volumes1,2,3,4and5) I-141 CONTRIBUTORS IrshadAhmad ArgonneNationalLaboratory,USA ThomasE.Albrecht-Schmitt AuburnUniversity,Alabama,USA MarkR.Antonio ArgonneNationalLaboratory,USA A.J.Arko LosAlamosNationalLaboratory,USA(retired) JamesV.Beitz ArgonneNationalLaboratory,USA(retired) JeanBlaise LaboratoireAime´Cotton,Orsay,France Jean-PhilippeBlaudeau HighPerformanceTechnologies,Inc.,Wright-PattersonAirForceBase,Ohio,USA NicholasJ.Bridges TheUniversityofAlabama,USA EdgarC.Buck PacificNorthwestNationalLaboratory,Richland,Washington,USA CarolJ.Burns LosAlamosNationalLaboratory,USA BruceE.Bursten TheUniversityofTennessee,USA GregoryR.Choppin FloridaStateUniversity,USA DavidL.Clark LosAlamosNationalLaboratory,USA ix x Contributors ClaudeDegueldre PaulScherrerInstitute,Switzerland PeterK.Dorhout ColoradoStateUniversity,USA JanuszDroz˙dz˙yn´ski UniversityofWroclaw,Poland PatriciaW.Durbin LawrenceBerkeleyNationalLaboratory,USA NormanM.Edelstein LawrenceBerkeleyNationalLaboratory,USA MorisS.Eisen Technion-IsraelInstituteofTechnology,Israel P.GaryEller LosAlamosNationalLaboratory,USA(retired) MarkFred ArgonneNationalLaboratory,USA(deceased) BlandineFourest InstitutdePhysiqueNucle´aire,Orsay,France JeanFuger UniversityofLie`ge,Belgium TakeoFujino TohokuUniversity,Japan(retired) IngmarGrenthe RoyalInstituteofTechnology,Stockholm,Sweden KeithE.Gutowski TheUniversityofAlabama,USA RichardG.Haire OakRidgeNationalLaboratory,USA JohnM.Haschke ActinideScienceConsulting,Harwood,TX,USA

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4059 Pages·2006·39.969 MB·English
by  Joseph J. Katz, Lester R. Morss, Norman M. Edelstein, Jean Fuger (auth.), Lester R. Morss, Norman M. Edelstein, Jean Fuger (eds.)
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Author:Joseph J. Katz, Lester R. Morss, Norman M. Edelstein, Jean Fuger (auth.), Lester R. Morss, Norman M. Edelstein, Jean Fuger (eds.)
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