Table Of ContentSINTERING '87
VOLUME 1
Proceedings of the 4th International Symposium on Science and Technology of
Sintering held in Tokyo, on 4-6 November, 1987
SINTERING '87
VOLUME 1
Edited by
SHIGEYUKI SOMIYA
The Nishi Tokyo University, Tokyo, Japan
MASAHIKO SHIMADA
Tohoku University, Sendai, Japan
MASAHIRO YOSHIMURA
Tokyo Institute of Technology, Yokohama, Japan
and
RYUZO WATANABE
Tohoku University, Sendai, Japan
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WITH 85 TABLES AND 609 ILLUSTRATIONS
© 1988 ELSEVIER SCIENCE PUBLISHERS LTD
Softcover reprint of the hardcover 1st edition 1988
British Library Cataloguing in Publication Data
International Symposium on Science and
Technology of Sintering
Sintering '87
1. Sintering
I. Title
671.3'73
ISBN-13: 978-94-010-7112-3 e-ISBN-13: 978-94-009-1373-8
DOl: 10.1007/978-94-009-1373-8
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To:
Professor Emeritus Toshiyoshi Yamauchi,
Tokyo Institute of Technology;
Professor Emeritus Yunishin Imai,
Tohoku University;
they encouraged us to organize Sintering '87 Tokyo.
VII
Organizers
• International Institute for the Science of Sintering
• Organizing Committee for the '87 International Symposium on Science and Technology
of Sintering
• The Nikkan Kogyo Shim bun, Ltd
Co-Sponsors
Ministry of Education, Science and Culture The Association of Powder Process Industry
Ministry ofInternational Trade and Industry & Engineering Japan
Science and Technology Agency The Cement Association of Japan
Japan Society for the Promotion of Science The Ceramics Society of Japan
Science of Council of Japan The Chemical Society of Japan
Electronic Materials Manufacturers Associ The Electrochemical Society of Japan
ation of Japan The Iron and Steel Institute of Japan
Japanese Society of Electron Microscopy The Japan Industrial Furnace Manufac-
Japan Automobile Manufacturers Associ turers Association
ation, Inc. The Japan Institute of Metals
Japan Cemented Carbide Tool Manufac- The Japan Iron and Steel Federation
turers Association The Japan Society for Composite Materials
Japan Chemical Industry Association The Japan Society of Applied Physics
Japan Fine Ceramics Association The Japan Society of Mechanical Engineers
Japan Fine Ceramics Center The Materials Science Society of Japan
Japan Light Metal Association The Materials Process Technology Center
Japan Porcelain Insulator Manufacturer's The Society of Japanese Aerospace Co., Ltd
Association The Society of Materials Science, Japan
Japan Powder Metallurgy Association The Society of Non-traditional Technology
Japan Small Tools Association The Society of Powder Technology, Japan
Japan Society of Powder and Powder Metal The Technical Association of Refractories,
lurgy Japan
Japan Society of Precision Engineering Tungsten and Molybdenum Industries As
The Japanese Society for Non-Destructive sociation of Japan
Inspection
Advisory and Organizing Committee
Honorary Advisory Committee International Advisory Commili.:e
FUKUI, Shinji CHAKLADER, A. C. D. (Canada)
(Late) HASHIMOTO, Uichi EASTERLING, K. E. (Sweden)
IMAI, Yunoshin KISLY, P. S. (USSR)
KA WASHIMA, Chihiro KUCZYNSKI, G. c. (USA)
KOTO, Hajime MASUDA, Y. (Japan)
MA TSUY AMA, Yoshiharu MOON, I. H. (Korea)
(Late) MORIY A, Taro MURRAY, M. 1. (Australia)
NODA, Tokichi PASTOR, H. (France)
SHIRAKI, Yoichi PETZOW, G. (FRG)
T AGAI, Hideo RISTIC, M. M. (Yugoslavia)
T AKEI, Takeshi SCHATT, W. (GDR)
TASHIRO, Megumi SOMIY A, S. (Japan)
WAKABA Y ASHI, Shoji SPRIGGS, R. M. (USA)
YAMAUCHI, Toshiyoshi UPADHY A Y A, G. S. (India)
VINCENZINI, P. (Italy)
WALDRON, M. (UK)
YEN, T. S. (China)
viii
Domestic Advisory Committl'p
ANDO, Ken-ichiro OHTA , Toyohiko
DOTE, Akira OHTA, Zenzo
FUKAGAWA, Tadashi ONOUE, Yasuhara
FUKAGAWA, Yajiro SAEKI, Osamu
FUKUURA,lsamu SAITO, Hajime
FURUNO, Tomosuke SAITO, Shinroku
HACHISUKA, Eiji SATA, Toshiyuki
HAYA KAW A, Shigeru SUZUKI, Hiroshige
HAY AMA, Fusao SUZUKI, Hisashi
HOSOKI, Shigeo T AKADA, Toshio
IMAGAW A, Hikoji TAKEMOTO, Kunihiro
INAMORI, Kazuo TANAKA, Hirokichi
ISHIHARA, Kiyoshi TANAKA, Masami
ITO, Kazuo UENOHARA, Michiyuki
IW AO, Hiromu UMEDA, Natsuo
KASE, Kaoru W AKINO, Kikuo
KATORI, Kazuo W AT ANABE, Hideo
KOMATSU, Wazo W AT ANABE, Hiroshi
KOTERA, Yoshihide YAMADA, Toshiro
KUNO, Hiroshi YAMAMOTO, Masao
KUNUGI, Masanaga YAMAMOTO, Noboru
MITA NI, Hiroyasu YOKOYAMA, Ryoji
MORIYA, Hiroyuki YOSHIMARU, Kiyoharu
NAKAHARA, Tsuneo
Organizing Committee
* Executive Committee member KAT O, Etsuro
KAWADA, Naoya
ABE, Toshio KAWAI, Shichio
ARAKIDA, Yutaka KAWAKITA, Tooru
BAN DO, Y oshichika KAWANAMI, Toshio
BAN NO, Hisao KITA ZA W A, Koichi
FUEKI, Kazuo· KOBAYASHI, Kazuo
FUKATSU, Tamotsu KOIZUMI, Mitsue
FUKUNAGA,Osamu* KOKUBO, Ichiro
HAMANO, Kenya KONDA, Noboru
HAMANO, Yoshiteru MASAKI, Takaki
HARADA, Hideki MASUDA, Yoshimichi
HAY AMI, Ryozo MASUMOTO, Takeshi
HAYASHI, Koji MINO,Iwao
HIRAI, Toshio* MITOMO, Mamoru*
HIRANO, Shin-ichi MIYAMOTO, Hiroki
HORIE,lsao MIYAMOTO, Yoshinari
ICHINOSE, Noboru* MIY ASH IT A, Tsuneo
IKEGAMI, Takayasu MORIYOSHI, Yusuke*
INOMATA, Yoshizo MURAl, Terumi
ISHIKAWA, Mitsuo NAGAI, Hiroshi*
IWATSU,Osamu NAGAI, Haruya
KAMINO, Kimiyuki NAGASE, Toshiharu
KANAMARU, Fumikazu NAKA, Shigeharu
KATO, Akio NAKAGAWA, Kuniyoshi
ix
NAKAGA W A, Ryuichi SHOJI, Keiichiro
NAKAGA WA, Takeo SOGA, Naohiro
NAKAGA W A, Zenbe-e* SOMIY A, Shigeyuki (Chairman)*
NAKANISHI, Norihiko* SUDO, Hajime
NAKAYAMA, Jun SUGAI, Mikio
NIIHARA, Koichi T ABA T A, Hideyo*
OHNO, Tomeji TAKAHASHI, Katsuaki
OKADA, Takashi TAKAHASHI, Mitsuo
OKABE, Kyoji TAKAJO, Shigeaki*
OKAZAKI, Kiyoshi TAKEDA, Toru*
OKUDA, Hiroshi TOKUNAGA, Yoichi
OKUMURA, Miyuki TOYOTA, Manzo
ONO, Mikiya UCHIKA W A, Hiroshi
OTSUKI, Shotaro USHIGOME, Susumu
SABURI, Katsuo WATANABE, Ryuzo*
SAKUMA, Taketo WATANABE, Teruhisa
SATOH, Takehiko YAMAGUCHI, Takashi*
SA WAOKA, Akira YAMAMOTO, Takuro
SETAKA, Nobuo YANAGIDA, Hiroaki
SHIMADA, Heihachi YASUDA, Eiichi*
SHIMADA, Kinji Y AZU, Shiuji
SHIMADA, Masahiko* YOSHIMURA, Masahiro*
SHIRASAKI, Shin-ichi YOSHITOME, Hiroshi
xi
PREFACE
The 4th International Symposium on Science and Technology ofSintering was held
on 4-6 November 1987, in Tokyo, under the auspices of the organising committee,
the International Institute for the Science ofSintering and Nikkan Kogyo Shimbun
Ltd.
The first meeting was held in Yugoslavia in 1975, the second was in Poland in 1979
and the third was in India in 1983. The fourth was in Tokyo in 1987.
Participants numbered about 500, including 100 from abroad. These came
from USA, France, FRG, China, Australia, Korea, Sweden, Yugoslavia, GDR,
India, Czechoslovakia, Brazil, Italy, Spain, Canada, Taiwan, etc.
We had many good presentations and discussions during the meeting and were
informed about the present status of the science and technology of sintering.
Understanding and mutual human relations were promoted by this meeting. The
meeting was a success and these proceedings will promote the science and
technology of sintering.
SHIGEYUKI SOMIY A
MASAHIKO SHIMADA
MASAHINO YOSHIMURA
Ryuzo WATANABE
X11I
CONTENTS
Organizers and Co-Sponsors vii
Advisory and Organizing Committee. VB
Preface XI
VOLUME I
International Institute for the Science ofSintering-The Community of the
World's Scientist and the Foundation of Sintering Future
MOMCILO M. RISTIC
Chemical Synthesis and Sol-Gel Processing
The Powder Preparation of La2T i20 7 and La4T i90 24 Using Amorphous
Complex Colloid and the Sintering Behaviour of the Synthesized Powders 7
1. TAKAHASHI
Preparation and Properties of Monodispersed Ceramic Powders 13
TAKASHI OGIHARA, KAZUO SHINOZAKI, NOBUYASU MIZUTANI AND
MASANORI KATO
Occurrence of Priderite in the K20-AI20 3-Ti02 System 19
HITOSHI OHSATO, SHOJI OKUDA AND IWAO MAKI
Preparation and Electrical Conductivity of Polyc rystalline M +- p"-Ferrites
(M +: K +, Rb + and Cs+) with p"-Alumina Structure 25
SHiNYA NARIKI, KATSUMI UCHINOKURA, SHIGERU ITO AND NOBORU
YONEDA
Synthesis and Sintering of Platelike CaO-Stabilized Zr02 Crystals. 31
ETSURO KA TO AND CHUNTING LI