Physico-Chemical Constants of Binary Systems in Concentrated Solutions, Volume 3 - Systems with Metallic Compounds

1339 Pages·1960·56.146 MB·English

by  Timmermans, Jean

The
Physico- chemical Constants
of Binary Systems
in Concentrated Solutions
VOLUME 3
SYSTEMS WITH METALLIC COMPOUNDS
by JEAN TIMMERMANS
Hon. Professor, Universite Libre, Brussels, Belgium
1960
I N T E R S C I E N C E PUBLISHERS, INC., N E W YORK
INTERSCIENCE PUBLISHERS LTD., LONDON
Copyright 0 1960 by Interscience Publishers, Inc.
Library of Congress Catalog Card Number 59-8839
Interscience Publishers, Inc., 250 Fifth Avenue, New York 1, New York
For Great Britain and Northern Ireland:
Interscience Publishers Ltd., 88/90 Chancery Lane, London W. C. 2, England
Printed in the United States of America
VII
Preface to Volume 3
In this third volume, ue have collected eters are accurately calibrated, some authors
all the numerical data puhlished about con- made the mistake of not taking into account
centrated hinary mixtures uith at least one the correction for the emergent column, which
metallic compound. is positive or, for low temperatures, negative;
with electrical thermometers, where the ac-
lo prepare this volume ue have received
curacy can be much greater, there are errors
substantial grant from the Union Minikre du
connected with the temperature coefficient of
Haut-Katanga, Hhich IS especially interested
the resistant coils, if the thermostat is not
in this kind of binary systems, and we wish
very good: in viscosity measurements, the
to thank heartily this big Society for its
method of Poiseuille is accurate only if the
support.
diameter of the capillary, relative to its
As in the former volumes, there are in
length, is adequate; and so on.
some cases considerable discrepancies between
Today, all physical chemists who want to
the data given by different authors; this is
make accurate measurements should test their
due not only to some impurity of the chemical
physical methods with great care.
samples hut also to the use of experimental
methods or apparatus which are not aluays Brussels
Jean Timmermans
adequate, For example, even if the thermom- October, 1959
Xlll
Contents
.....................................................
Preface to Volume 3 vi i
........................................................
Notice for users ix
.
N Tho Metallic Salts
XL TWO metallic salts Hith the same anion (fluorides and chlorides) 1
........................................
XL I Other binary compounds 81
.................................................
XLII Two oxy salts 149
.................................
SLIII Two salts with the same metal 215
.
0 Water + Salts of Monovalent Metals
..........................
XLIY Water + sodium salts (halogen salts) 302
...................................
XLV Water + sodium monoxy salts 364
......................
XLV I Water + sodium polyoxy and organic salts 423
..............
XLVI I Water + potassium salts (halogen and hydroxides) 170
...................................
XLVIII Water + potassium oxy salts 549
......................
XLIX Water + salts of other monovalent metals 612
.
P Water + Salts of Polyvalent Eletals
...........................
L Water + salts of Be. Mg. Sn. and Pb 700
.........................
LI Water + salts of alkaline earth proup 748
...............................
LI I Water + salts of Zn. Cd. and Hg 838
.......................
LIII Water + salts of Cu. Mn. Fe. Ni. and Co 897
......................
LIV Water + salts of other polyvalent metals 965
.
Q Metallic Salts + Other Solvents
.............................
LV Metallic salts + organic solvents 1031
.........................
LV I Metallic salts + hydroxyl derivatives 1162
....................
LVII Metallic salts + other inorganic compounds 1223
LITHIUM FLUORIDE t SODIUM FLUORIDE 1
11
pi. W0 hIETALLIC 5ALTS
XL. T1V0 METALLIC SALTS WITH THE SAME AhIOR
muorides and Chlorides)
--"
n n wn
;.42 i.b5 830 818 12
19.62 16.98 810 785 25
29.35 25.83 785 750 35
39.30 35.20 750 720 30
44.25 39.90 725 700 25
49.21 44.54 70 0 6 85 15
54.15 49.69 6 a5
0 844 59.1 54.79 6 75
39 652 E -
100 990 6638..625 5694..5257 66 6790 -
73.70 69.99 682
78.73 75.71 690
88.5 86.59 1060
100 100 14-00
0 844
492 E 0 844
100 85 6 33 742 E
100 1080
Lithium fluoride ( LiF ) + Beryllium fluoride
( BeFz )
0 84 2 30 736
10 815 32 724 E
20 765
0 845 47.5 400 350
10 780 465 48.7 390 355
20 700 470 50 365
27.5 5 70 465 52 360
30 500 472 53 365
31.5 462 57 367
33.3 475 60 365
36.0 475 (350) 63 360
38.0 453 (34.5) 67 41 7 370
40 445 340 70 417 365
42.5 440 340 73 420 365
54.0 420 340 80 431 370
II
I
Roy, Roy and Osborn, 1950 ( fig. )
mold f.t. E mold f.t. E 0 870
10 830 800 670
0 870 51 356 356 20 790 770 720
456 70 480 356 36 7.35 735 735
20 4;6 4.56 80 520 356 50 9 80 830 735
358 - 100 540 60 1080 910 7.30
3403 430 456 80 1210 1090 715
100 1280
2 LITHIUM FLUORIDE t BERYLLIUM FLUORIDE
B f.t. tr.t.1 tr. t.11 tr.t. I11 tr.t. IV
- -
0 845 - -
9.0 831 464 1.5 -
13.5 820 462 4.0
13.6 458
18.6 812 461 5.0 -
23.8 773 460 6.0 -
25.0 774 457 6.0
25.6 784 459 7.0
30.4 722 465 9.0
31.7 782 460 10.0
36.0 682 465
37.8 662 465
40.1 603 461
41.8 571 457
43.1 5 70 458 -
46.0 485 461 12.0
47.1 562 460
47.5 560 460
47.5 460 12.0 -
49.4 460 8.5
51.7 478 460 7.5 306 1
52.4 450 - - 348 3
52.9 452 - - 348 4
53.8 448 - 347 4
54.7 433 - 340 3.5
55.8 432 359 3
57.8 428 361 4.5
58.9 422 355
61.3 390 351 4.5
62.6 390 - 341 6.0
63.8 379 357 7.0
$ f.t. m.t. E min. E min. tr.t. tr.t.1 tr.t I1
f t m.t. min min. min
666786...963 ---- 333564301 333776007 1980...050 34--6 7.---0 --- -- 3333- 80 0---. 3 ---- -*-
70.6 - 352 369 9.5 - - -
71.2 364 372 8.5 - 337 0.7 -
77777353....1953 344926- 200 333364552777 333366673187 6848....0455 334491 87..55 222848144 06..52 3-3-- 8 0---.- 8 222111505 -
77.7 465 443 368 5.0 362 8.0 213 0.- 3
78.6 486 431 369 5.0 347 7.0 252 4.5 339 1.0 2-1 7
79.4 483 413 374 4.5 340 7.0 260 5.8 33- 0 1-. 0
80.3 490 441 373 4.5 3 70 7.5 216 0.3
8802..93 459053 442347 337633 44..55 334540 77. 5 27-- 8 5.-5 33- 7 1.-0 222138 -
888864...544 555210878 4422-6 3 333677800 443...000 334533 57..55 238- 2 31..50 333444127 211...550 21-- 2 --
90.5 537 450 368 2.5 348 4.5 0.5 337 4.0 2-21 0.3
92.4 532 461 370 2.5 344 6 314 3.0
9946..40 554430 445511 337617 01..55 334377 33..55 - -- 3323- 63 45..-55 22-1- 0.- 3
9997..99 555647 445496 3355-93 - 339 3 - -- - 3-87 -- 22-1178 00 ....6 7
100 577
LITHIUM FLUORIDE t CALCIUM FLUORIDE 3
Lithium fluoride ( LiF ) + Calcium fluoride
( CaF2 )
0 860 560
2.5 848 715
5.0 830 715 35.0 722
10.0 784 715 36.0 710 710E
0 848 24.3 816 12.5 75.5 715 37.5 726 7:0
1.6 840 26.6 84 2 15.0 715 715 E 40.0 755 ,,
3.1 833 29.1 867 17.5 750 715 45.0 853 ,,
4.8 825 31.6 895 20.0 770 715 50.0
6.4 817 34.3 916 25.0 790 715 (3+1)
8.2 810 37 940
9.9 804 39.9 962
11.8 796 42.9 986
13.7 79 1 46 1012
15.7 782 49.3 1036 Sodium fluoride ( NaF + Potassium fluoride ( KF
17.7 776 52.7 1062
19.8 769 E 56.3 1090
22 792
0 997.0 - 55.4 699 699
151..8343 996478 70--0 6605 771663 69-9
22 44 899 73.8 771 697
33.16 847 80 788
42.66 790 85.0 812
48.2 770 699 89 67 812
53.1 743 100 837
25.0 783 70.0 884
30.0 768 75.0 916 0 997
32.5 760 75.0 920 tr.t. 60 700
32.0 760 E 77.5 964 100 837
15.0 766 964
100 854 852 55 744 743
90 824 823 50 774 772
80 791 790 45 801 799
70 756 756 40 825 824
65 735 734 30 878 877
60 717 716 20 919 918
0 870
5 828 71 0
8 790 703 3.0 (3~1)
12.5 730 700 4.6
14.5 706 706 11.4
19.0 750 700 2.2
22.5 783 690 0.6
27 780 661 1.2
30.5 737 6 89 4 3
32.5 728 689 7.4
337 - 691 8.7
4 SODIUM FLUORIDE t BERYLLIUM FLUORIDE
Sodium fluoride ( KaF) + Beryllim fluoride (BeF,)
Thilo and Schdder, 1951
molg f.t E mol% f.t. E
Novoselova, Levina and al., 1944
0 38 480
wt% molgk f.t. E min. 10 555 39 415
15 565 40 375
18 560 40 348
0 0 1024 21 560 42 342
2.15 1.92 1006 5 80 1 25 560 44.3 340
5.51 4.95 935 590 1 26 560 47 358
11.30 10,21 827 580 1.5 28 57 0 50 372
17.79 16.20 715 580 1.0 29 565 52.5 360
20,oo 18.25 664 590 1.7 31 560 55 355
21.50 19.66 6 24 5 80 2.0 32 560 61.4 340
23 11 21 16 6 20 5 80 2.3
33. 75 345
24 98 22.93 580 580 2.0
29,19 24.91 6..0 4 580 35 83 345
32 00 29.kQ 609 580 1.7
35.32 32 79 620 ( 1+1 ) (2+1) (3+2)
37.90 35.27 536 353 1.- 0
39.89 37.22 520 360 1.7
41: 08 38.39 517 360 Roy, Roy and Osborn, 1950 (fig.)
42.58 39.86 470 360 2.-1-
43.21 40 46 456 353 molgk tr. t. molgk tr.t.
45.80 43.02 377 360
53.00 50.19 440 360
56.81 54.03 4 70 50 381 80 510
6604..4211 6571..6597 52- 8 5706 437750 E 19000 553400
69.53 67.09 602
75.75 73.63 6 82
85.82 84.37 734 Sodium fluoride ( NaF) +'Elagnesium fluoride ( MgF,:
94.97 94.: 47 744
100.00 100 00 is0
(i+2 Bergman and Dergunov, 1941 and 1945 ( fig.)
min. mol$ f.t. molgk f.t.
I I1
0 1000 50 1030
10 960 64 957
2.15 220 0.7 25 80 1100
5.51 220 - 0.7 816 1.1 +1~) .
11.30
17.79 322 220 0.7 1.0
20,oo 220 1.0 Sodium fluoride ( NaF + Barium fluoride ( BaF, 1
21 50 322 22 0 0.7 1.6
23.11 220 1.3
24 98 322 220 0.7 1.6 Grube, 1927
29 19 340
32.00 320 220 1.0 2.0
35.32 330 222 2 0 2.3 % f.t. E min.
37.90 330 222 1.5 2.0 -
43.91~.. .30.93 ._33_m0_ 220 1.5 2.0 n 992 -
42.58 330 220 1.3 0.7 817 47
43.21 323 1.0 813 70
(2+1) 823 93
823 117
wtgk tr. t. (1+1) tr.t. BeFz 825 135
823 162
I I1 min. I I1 316 188
- a21 210
5435..0800 373 - - 430 382215 223549
56.81 360 - 825 290
60.41 370 - 822 337
64-21 360 290 8 823 425
69.53 360 295 10 411 823 365
75.75 374 284 5 819 297
35.82 390 23- 4 5 459 814 220
94.97 372 473 81- 6 14- 5
1--0_0_._0 0 525 -_42_5 _ -
SODIUM FLUORIDE t CALCIUM FLUORIDE 5
Sodium fluoride ( NaF) + Calcium fluoride ( CaF,)
Sodium fluoride ( NaF) + Lead fluoride ( PLF,)
Fedotiev and Iljinski, 1923
Puschin and Baskov, 1913
mol% f.t. E nin.
100 100 1360
70 81.3 1090 0 1040
50 65.0 950 10 990 540 1.7
32.5 47.2 810 20 930 542 2.3
20 31.7 8 80 30 872 545 3.-4
10 17.1 935 40 325 538 -
0 0 990 50 740 540 -
60 628 538 -
66.5 560 540
69.5 575 540 5.0
76.5 643 545 3.5
Grube and Ilenne, 1930 85 710 531 1.9
100 855
II
100 1330 40 840 803 Gladushciienko and Bergnan, 1955
80 1123 796 30 896 80 4
6700 1900120 789081 2100 993617 8709- 81 mol% f.t.
50 81- 2 803 0 992 ~~ ~
47.2 803 0 990
62.1 498 E
100 860
Sodium fluoride ( NaF) + Zinc fluoride ( ZnF,)
Puschin and Baskov, 1913
Puschin and Baskov, 1913
no12 f.t. E nin. tr.t. min.
0 1040
5.5 983 660 2.1
13.5 940 665 4.3 0 1040 1040
12030 .0 980752 682 5-.8 72. 5 11003000 993305 02..66 600 0.7
11 978 932 3.8
14.5 943 935 7.5
18.5 973 920 4.9 603 3.3
990 923 4.4 600 3.9
l291 1005 91-0 602
Sodium fluoride ( NaF) + Cadmium fluoride ( CdF,) 2253 .5 11001273 - 660000 4.1
28 1010 742 0.5
30 995 740 5.8 603 1.0
Puschin and Baskov, 1913 30.5 985 740 4.1 600
31.5 950 743
32 945 740 7.4
mol$ f.t E min. 35 860 740 1.12
40 737 -(3+1) -
0 1040
9 995 645 3.1
13.5 970 650 4.6 Fedotieff and Iljinski, 1913
23 895 655 5.5
3454 .5 677708 665650 97..38 mol$ f.t.
54.5 746 660 5.6
65 885 655 2.4 100 1000
90 1040 640 1.0 14 885 E
100 1110 0 990
6 SODIUM FLUORIDE t FERRIC FLUORIDE
Sodium fluoride ( NaF) + Praseodymium fluoride
Lorenz, Jobs and Eitel, 1913 ( PrF3)
B f.t E min.
Dergunov, 1952 ( fig.)
100
37.6 884 2.7 moli f.t. mol% f.t.
32.4 884 5.0
26.8 887 7.9
25.0 889 8.1 0 992 30 780 E
21 7 895 1L 0.8 10 950 35 800
0 985 15 920 45 880
I 20 835 50 945
Fedotieff and Iljinski, 1913 and 1924
II mol$ wt$ f.t. Potassium fluoride ( KF) + Rubidium fluoride ( RLF)
El min. €2 nin. tr.t min
- - - - Dergunov and Bergman, 1948
0 0 990 - - -
34 57..8629 998700 875 0.2 - - 56" 5 0.2 mol% f.t. mol% f.t.
5 9.52 955 875 2 - " 0.8
111450 221468.. 511603 998028005 888858055 268 ..70 -- -- 563 1i..23 1990050 777888001 443505
2203 3337 .4303 999505 8887- 05 40..31 -- --- 565 22..15 5305 778322 3205
3433205570 ..44 4455570641.....4081380573 1997803185005050 725 5567. ..555 6678-- 55 01--..5 5 ---I11t 02I --..2 5 7766500555 777775889845823 11205005
42.3 59.45 720 -I' - 675 2.5 - - 50 797
4456 .6 6632..5102 670805 -- -- 668t50 160 .5 -- -- Mixed crystals
544078 ..45 666645...633722 677-9 05 68-- 5 - 98 - --- --_ -
Potassium fluoride ( KF) + Magnesium fluoride
( MgF, 1
Elcliardus, 1938 Rcny and Seeman, 1940
nolk f t. mln tr.t.1 min.
100 1260 3.0
j/ 0 12 8 9800 11211455 -- 11002200 01..255
14.5 70 1045 1019 5.0
;;.5 13.4 68 1020 7 .o
10.6 60 1065 1010 1.25
50 1080 3.0
4 5 1072 1063
40 1055 1040
35 1094 Y40
Sodium fluoride ( NaF) t Ferric fluoride ( FeF3) 33.3 970 859 0.5
30 R90 350
25 850 840 0.25
21.5 840 732 1.5
Pusciiin and Baskob, 1913 2c 822 782 2.0
17.5 865 792 2.75
molk f.t. E mol% f.t E 1152 .5 773902 3.25 701 3.0
10 793 780 1.5
0 1040 25 975 895 1.5 797 750 1.25
885 30 945 890 5 810 750 0.5
15 1005 890 3 5 892 0 848 2.6
U--