Table Of ContentNMR of
Quadrupolar
Nuclei in
Solid Materials
EMR Handbooks
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NMR of
Quadrupolar
Nuclei in
Solid Materials
Editors
Roderick E. Wasylishen
University of Alberta, Edmonton, Canada
Sharon E. Ashbrook
University of St Andrews, St Andrews, UK
Stephen Wimperis
University of Glasgow, UK
A John Wiley and Sons, Ltd., Publication
Thiseditionfirstpublished2012
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LibraryofCongressCataloging-in-PublicationData
NMRofquadrupolarnucleiinsolidmaterials/editors,RoderickE.Wasylishen,
SharonE.Ashbrook,StephenWimperis.
p.cm.
IncludesIndex.
ISBN978-0-470-97398-l(cloth)
1. Nulclearquadrupoleresonancespectroscopy.2. Nuclearspin.3. Solids–Analysis.
I.Wasylishen,RoderickE.II.Ashbrook,SharonE.III.Wimperis,Stephen.
QD96.N84N572012
538’.362–dc23
2012002021
AcataloguerecordforthisbookisavailablefromtheBritishLibrary.
ISBN-13:978-0-470-97398-1
Setin9.5/11.5ptTimesbyLaserwords(Private)Limited,Chennai,India
PrintedandboundinSingaporebyMarkonoPrintMediaPteLtd
Encyclopedia of Magnetic Resonance
Editorial Board
Editors-in-Chief
RobinK.Harris RoderickE.Wasylishen
UniversityofDurham UniversityofAlberta
Durham Edmonton,Alberta
UK Canada
Section Editors
SOLID-STATE NMR & PHYSICS
MelindaJ.Duer BernardC.Gerstein
UniversityofCambridge Ames,IA
Cambridge USA
UK
SOLUTION-STATE NMR & CHEMISTRY
JamesW.Emsley GeorgeA.Gray GarethA.Morris
UniversityofSouthampton VarianInc. UniversityofManchester
Southampton PaloAlto,CA Manchester
UK USA UK
BIOCHEMICAL NMR
AnnE.McDermott TatyanaPolenova
ColumbiaUniversity UniversityofDelaware
NewYork,NY Newark,DE
USA USA
MRI & MRS
JohnR.Griffiths VivianS.Lee IanR.Young
CancerResearchUK NYULangoneMedical ImperialCollege
CambridgeResearch Center London
Institute NewYork,NY UK
Cambridge USA
UK
HISTORICAL PERSPECTIVES
EdwinD.Becker
NationalInstitutesofHealth
Bethesda,MD
USA
vi Encyclopedia of Magnetic Resonance
International Advisory Board
David M. Grant(Chairman)
University of Utah
Salt Lake City, UT
USA
Isao Ando Adriaan Bax Chris Boesch
Tokyo Institute National Institutes of Health University of Bern
of Technology Bethesda, MD Bern
Tokyo USA Switzerland
Japan
Paul A. Bottomley William G. Bradley Graeme M. Bydder
Johns Hopkins University UCSD Medical Center UCSD Medical Center
Baltimore, MD San Diego, CA San Diego, CA
USA USA USA
Paul T. Callaghan Richard R. Ernst Ray Freeman
Victoria University Eidgeno¨ssische Technische University of Cambridge
of Wellington Hochschule (ETH) Cambridge
Wellington Zu¨rich UK
New Zealand Switzerland
Lucio Frydman Maurice Goldman Harald Gu¨nther
Weizmann Institute Villebon sur Yvette Universita¨t Siegen
of Science France Siegen
Rehovot Germany
Israel
Herbert Y. Kressel C. Leon Partain Alexander Pines
Harvard Medical School Vanderbilt University Medical University of California
Boston, MA Center at Berkeley
USA Nashville, TN Berkeley, CA
USA USA
George K. Radda Hans Wolfgang Spiess Charles P. Slichter
University of Oxford Max-Planck Institute University of Illinois
Oxford of Polymer Research at Urbana-Champaign
UK Mainz Urbana, IL
Germany USA
John S. Waugh Bernd Wrackmeyer Kurt Wu¨thrich
Massachusetts Institute Universita¨t Bayreuth The Scripps Research
of Technology (MIT) Bayreuth Institute
Cambridge, MA Germany La Jolla, CA
USA USA
and
ETH Zu¨rich
Zu¨rich
Switzerland
Contents
Contributors ix
Series Preface xiii
Volume Preface xv
PartA:BasicPrinciples 1
1 QuadrupolarInteractions
PascalP.Man 3
2 QuadrupolarNucleiinSolids
AlexanderJ.Vega 17
3 QuadrupolarCoupling:AnIntroductionandCrystallographicAspects
SharonE.Ashbrook,StephenWimperis 45
4 QuadrupolarNucleiinSolids:InfluenceofDifferentInteractionsonSpectra
DavidL.Bryce,RoderickE.Wasylishen 63
PartB:AdvancedTechniques 75
5 AcquisitionofWidelineSolid-StateNMRSpectraofQuadrupolarNuclei
RobertW.Schurko 77
6 SensitivityandResolutionEnhancementofHalf-IntegerQuadrupolarNucleiinSolid-StateNMR
ThomasT.Nakashima,RoderickE.Wasylishen 95
7 QuadrupolarNutationSpectroscopy
ArnoP.M.Kentgens 107
8 DynamicAngleSpinning
PhilipJ.Grandinetti 121
9 DoubleRotation(DOR)NMR
RayDupree 133
10 MQMASNMR:ExperimentalStrategies
Jean-PaulAmoureux,MarekPruski 143
11 STMASNMR:ExperimentalAdvances
SharonE.Ashbrook,StephenWimperis 163
12 CorrelationExperimentsInvolvingHalf-IntegerQuadrupolarNuclei
MichaelDeschamps,DominiqueMassiot 179
13 ComputingElectricFieldGradientTensors
JosefW.Zwanziger 199
viii Contents
PartC:Applications 211
14 QuadrupolarNMRtoInvestigateDynamicsinSolidMaterials
LukeA.O’Dell,ChristopherI.Ratcliffe 213
15 AlkaliMetalNMRofBiologicalMolecules
GangWu 233
16 Nitrogen-14NMRStudiesofBiologicalSystems
LuminitaDuma 255
17 Oxygen-17NMRStudiesofOrganicandBiologicalMolecules
GangWu 273
18 Oxygen-17NMRofInorganicMaterials
SharonE.Ashbrook,MarkE.Smith 291
19 Chlorine,Bromine,andIodineSolid-StateNMR
DavidL.Bryce,CoryM.Widdifield,RebeccaP.Chapman,RobertJ.Attrell 321
20 QuadrupolarNMRofIonicConductors,Batteries,andotherEnergy-RelatedMaterials
Fre´de´ricBlanc,LeighSpencer,GillianR.Goward 349
21 QuadrupolarNMRofNanoporousMaterials
MohamedHaouas,CharlotteMartineau,FrancisTaulelle 371
22 QuadrupolarNMRintheEarthSciences
JonathanF.Stebbins 387
23 QuadrupolarNMRofSuperconductors
NicholasJ.Curro 401
24 QuadrupolarNMRofSemiconductors
JamesP.Yesinowski 417
25 QuadrupolarNMRofMetalNuclidesinBiologicalMaterials
TatyanaPolenova,AndrewS.Lipton,PaulD.Ellis 439
26 NuclearWasteGlasses:InsightsfromSolid-StateNMR
ScottKroeker 453
27 QuadrupolarMetalNMRofOxideMaterialsIncludingCatalysts
OlgaB.Lapina,VictorV.Terskikh 467
28 QuadrupolarNMRofIntermetallicCompounds
FrankHaarmann 495
Index 511
