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Lecture 11: Reactions in Liquids PDF

9 Pages·2020·English
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by ['Ganesh Chandra Baro']| 2020| 9 pages| English

About Lecture 11: Reactions in Liquids

The document discusses reactions that occur in liquid solutions. It notes that reactions in liquids differ from gases due to molecules interacting continuously with the solvent. When reactants collide in solution, they often undergo multiple collisions while held close by solvent molecules before diffusing apart. The document presents a simple phenomenological model of reactions in solution involving reactants diffusing together to form an encounter complex, then either breaking apart or reacting. It derives expressions for the effective rate constant of reactions that are either diffusion limited or reaction limited. Finally, it generalizes the analysis to cases where the reaction is not purely diffusion or reaction limited.

Detailed Information

Author:['Ganesh Chandra Baro']
Publication Year:2020
Pages:9
Language:English
Format:PDF
Price:FREE
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