Table Of Contentइंटरनेट मानक
Disclosure to Promote the Right To Information
Whereas the Parliament of India has set out to provide a practical regime of right to
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in order to promote transparency and accountability in the working of every public authority,
and whereas the attached publication of the Bureau of Indian Standards is of particular interest
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education and knowledge, the attached public safety standard is made available to promote the
timely dissemination of this information in an accurate manner to the public.
“जान1 का अ+धकार, जी1 का अ+धकार” “प0रा1 को छोड न’ 5 तरफ”
Mazdoor Kisan Shakti Sangathan Jawaharlal Nehru
“The Right to Information, The Right to Live” “Step Out From the Old to the New”
IS 14375 (1996): Cyclohexanone [PCD 9: Organic Chemicals
Alcohols and Allied Products and Dye Intermediates]
“!ान $ एक न’ भारत का +नम-ण”
Satyanarayan Gangaram Pitroda
““IInnvveenntt aa NNeeww IInnddiiaa UUssiinngg KKnnoowwlleeddggee””
“!ान एक ऐसा खजाना > जो कभी च0राया नहB जा सकता हहहहै””ै”
Bhartṛhari—Nītiśatakam
“Knowledge is such a treasure which cannot be stolen”
IS 14375:1996
x-Y \u n
til~~lFWllll- IW
Indian Standard
CYCLOHEXANONE - SPECIFICATION
ICS 71.080230
@ BIS 1996
BUREAU OF INDIAN STANDARDS
MANAK BHAVAN, 9 BAHADUR SHAH ZAFAR IMARG
NEW DELHI 110002
yruJ 1996 ecirP puorG 3
cinagrO slacimehC (Mist) lanoitceS ,eettimmoC PCD 9
FOREWORD
sihT naidnI dradnatS was detpoda yb eht uaeruB fo naidnI Standards, retfa eht tfard dezilanif yb eht
cinagrO slacimehC (Mist) lanoitceS eettimmoC had neeb devorppa yb eht ,muelorteP laoC and detaleR
stcudorP noisiviD .licnuoC
enonaxeholcyC )Q.nH6C( is an tnatropmi lacimehc etaidemretni desu ni eht noitcudorp fo cipida ,dica
nolyn 6 and .matcalorpac tI is osla desu as a tnevlos and renniht rof sreuqcal yllaicepse esoht gniniatnoc
esolullecortin ro lyniv edirolhc remylop and remylopoc sniser gnidulcni edirolhclynivylop and -yrcahtem
etal retse .sremylop tI is an tnellecxe tnevlos rof surohpsohponagro .sedicitcesni tI osla sdnif esu as a
egduls tnevlos ni lio rof notsip epyt tfarcria .noitacirbul
ehT lacimehc nac esuac lacisyhp egamad eud ot degnolorp erusopxe and ti nac osla esuac etuca erif drazah
hguoht ti is evisolpxe-non ees( .)4
roF eht esoprup fo gnidiced rehtehw a ralucitrap tnemeriuqer fo this standard is deilpmoc ,htiw eht lanif
,eulav devresbo ro ,detaluclac gnisserpxe eht tluser fo a tset ro ,sisylana shall eb dednuor ffo ni ecnadrocca
htiw SI 2 : 1960 seluR‘ rof gnidnuor fo laciremun seulav .‘)desiver( ehT rebmun fo tnacifingis secalp
deniater ni eht dednuor ffo eulav dluohs eb eht emas as that fo eht deificeps eulav ni this standard.
IS14375:19!x
Indian Standard
CYCLOHEXANONE - SPECIFICATION
1 EPOCS ISN o, Title
sihT standard sebircserp eht stnemeriuqer and noitanimreteD fo retaw yb eht
2362_: 1973
sdohtem gnilpmasfo and tset rof .enonaxeholcyc lraK rehcsiF dohtem tsrif(
revision)
2 EVITAMRON SECNEREFER
2552 : 1979 leetS drums dezinavlag( and -nu
ehT gniwollof naidnI Standards era yrassecen -da )dezinavlag dnoces(
revision)
stcnuj ot this standard. ehT standards niatnoc 4905 : 1968 sdohteM rof modnar sampling
snoisivorp hcihw hguorht ecnerefer ni this txet -noc 8768 : 1988 dohteM fo tnemerusaem fo
etutits snoisivorp fo this standard. At eht emit fo ruoloc ni diuqil lacimehc
,noitacilbup eht snoitide detacidni erew .dilav llA stcudorp ni nezaH units tsrif(
standards era tcejbus ot ,noisiver and seitrap ot
_ revision)
stnemeerga desab no this standard era degaruocne
ot etagitsevni eht ytilibissop fo gniylppa eht tsom 3 STNEMERIUQER
tnecer snoisiver fo eht standards detacidni .woleb
3.1 noitpircseD
IS No. Title.
ehT lairetam shall eb sselruoloc diuqil htiw -carahc
1070 : 1992 retaW rof lareneg yrotarobal esu citsiret enoteca and tnimreppep ekil .ruodo tI shall
(third revision) eb eerf morf dednepsus rettam and .stnemides
1448 sdohteM fo tset rof muelortep
3.2 ehT lairetam shall osla ylpmoc htiw eht -er
traP( )81 : 1991 and its :stcudorp traP 18 -litsiD
stnemeriuq nevig ni elbaT 1.
noital dnoces(
revision)
elbaT 1 stnemeriuqeR rof enonaxeholcyC
Sl Characlerislic Kequirement dohteM fo Test, ReC to
No.
’ \
SI xennA ’
6 (2) (3) )1( (5)
9 Colour, nezaH ,stinU XUM 10 8768 : 3988 -
)ii retaW ,tnetnoc tnecrep yb ,ssam XUM 0.1 2362 : 1973
)iii noitallitsiD egnar ehT ecnereffid 1448 traP( 18) :
neewteb eht -pmet 1991
erutare gninnur( \
)stniop at hcihw 1
dna tnecrep69 fo
eht emulov nekat evah
neeb detcelloc llahs
ton deecxe 2% sihT
egnar llahs edulcni
eht erutarepmet fo 15%
)vi ytidicA sa( citeca ,)dica tnecrep yb 0.02 - A
,ssam xaM
)v sretsE lyhte( ,)etateca 50.0 - B
tnecrep yb ,ssam XQM
)iv ,ytiruP tnecrep yb ,ssam Min 99.8 - C
)iiv ,lonaxeholcyC tnecrep yb ,ssam 0.1 - C
MaU
)iiiv sC slohocla dna ,srehto tnecrep yb - C
,ssam Max
1
IS I4375 : 1996
4 SNOITUACERP NI GNILDNAH 5.3 BIS Certification Marking
enonaxeholcyC is ylno yletaredom erif suodrazah hcaE yamreniatnoc osla eb dekram htiw eht -dnatS
and .evisolpxe-non tI nac esuac suoires revil and
dra Mark.
yendik egamad fi eht erusopxe has neeb .taerg .tI is
ylthgils .elitalov tI sesuac noitatirri fo suocum -rus 5.3.1 ehT esu fo eht dradnatS Mark is denrevog yb
eht snoisivorp fo eht
ecaf yllaicepse .taorht ehT lairetam shall eb derots Bureau of Indian Standards
yawa morf nepo emalf and saera fp etuca erif Act, 1986 and eht seluR and snoitalugeR edam
.rednuereht ehT sliated fo snoitidnoc rednu hcihw
.drazah
eht ecnecil rof eht esu fo eht dradnatS Mark yam eb
5 GNIKCAP AND GNIKRAM detnarg ot srerutcafunam ro srecudorp yam eb -bo
deniat morf eht uaeruB fo naidnI Standards.
5.1 Packing
The lairetam shall eb dekcap ni 200 sertil dlim leets 6 SAMPLING
drums ees( SI 2552 : .)9791
evitatneserpeR samples fo eht lairetam shall eb
5.2
Marking drawn and rieht ytimrofnoc ot eht standard -reted
denim as debircserp ni xennA D.
ehT reniatnoc shall eb dekram htiw eht gniwollof
:noitamrofni
7 QUALITY OF REAGENTS
a>
emaN fo eht ;lairetam
b) emaN fo eht rerutcafunam and his -gocer Unless deificeps esiwrehto erup slacimehc and dis-
dezin edart ,kram fi ;yna dellit retaw ees( SI 1070 : )2991 shall eb desu ni
C> teN mass fo eht lairetam ni eht ;reniatnoc .stset
and
-ETON eruP‘ ’slacimehc llahs naem slacimehc taht od ton
4 toL ro hctab ,rebmun ni edoc ro .esiwrehto niatnoc seitirupmi hcihw tceffa eht stluser fo .sisylana
ANNEX A
[Table 1, SZN o. (iv)]
DETERMINATION OF ACIDITY
A-l PROCEDURE A-2 CALCULATION
hgieW tuoba 50 g fo elpmas ot eht tseraen 0.1 g ni ytidicA (as citeca ,)dica
6xNxV
500 lm reyemnelrE .ksalf Add 50 lm fo lartuen tnecrep yb mass = M
lyporposi iohocla htiw eht pleh fo rednilyc and _ _
swirl eht ksalf yltneg os that mrofinu gnixim fo
erehw
e,ht elpmas and eht lyporposi lohocla sekat
.ecalp etartiT eht tnetnoc fo eht ksalf htiw v = emulov ni lm fo muidos edixordyh
0.1 N muidos edixordyh noitulos using 10 spord ,noitulos
fo nielahthplonehp as .rotacidni ot knip N = ytilamron fo muidos ,edixordyh and
.noitaruoloc
mass ni g fo eht elpmas nekat rof .tset
M=
ANNEX B
[Table 1, SZN o. (v)]
NOI~TANIMRETED FO RETSE TNETNOC
l-B ENILTUO FO EHT DOHTEM 1.2-B dnuoR ksal%mottoB yticapac- 500 lm htiw
lamron dnuorg .tnioj
ehT retse tneserp ni eht elpmas era dewolla ot
ezylordyh ot sdica ni eht ecneserp fo cilohocla 2.2-B Reflux Condensers
muissatop .edixordyh ehT noitpmusnoc fo -la
3.2-B lm .yticapac
cilohoc muissatop edixordyh is a erusaem fo retse Volumetric Flasks - 250
.tneserp
-lortnoc
B-2.4 Heating Mantle -thermostatically
2-B SUTARAPPA .del
2
IS 14375 : 1996
B-3 REAGENTS eht stnetnoc ot lm-052 cirtemulov esU.ksalf
dezilartuen lonahte rof washing and ekam up.
B-3.1 Potassium Hydroxide in Ethanol (96 per- etuliD eht stnetnoc ot eht .kram refsnarT lm-52 fo
cent) - 0.5 N. hcae fo evoba tnevlos ot lm-052 lacinoc .ksalf Add
wef spord fo nielahthplonehp and etartit against 0.5
B-3.2 Hydrochloric Acid - 0.5 N.
N cirolhcordyh .dica
B-3.3 Phenolphthalein in Ethanol (96 Percent) -
1 .tnecrep B-5 CALCULATION
retsE tnetnoc as lyhte
B-4 PROCEDURE
b-a)xNx88
,etateca tnecrep yb mass = (
refsnarT 50 g fo dezilartuen-erp enonaxeholcyc ot M
lm-005 mottob-dnuor .ksalf Add lm-05 fo -lartuen
erehw
dezi lonahte and lm-05 fo 0.5 N muissatop
edixordyh htiw eht pleh fo lm-05 .ettepip -lumiS ertit eulav ni lm rof blank,
b =
ylsuoenat refsnart lm-05 fo dezilartuen lonahte a = ertit eulav ni lm rof ,elpmas
and lm-05 fo cilohocla muissatop edixordyh ot
N = ytilamron fo cirolhcordyh ,dica and
rehtona lm-005 mottob-dnuor .ksalf xulfeR htob
eht sksalf rof 45 .setunim looC dnaksalfeht refsnart M ~= mass ni g fo nekatelpmas rof .tset
ANNEX C
[Table 1, SZN o. (vi), )iiv( & ])iiiv(
DETERMINATION OF PURITY, CYCLOHEXANOI, Cs ALCOHOLS AND OTHERS
C-l OUTLINE OF THE METHOD negordyH/riA : roF mumixam esnopser l:O1
ria ot negordyh~ oitar
A small emulov fo enonaxeholcyc is detcejni otni a
saG hpargotamorhC gniniatnoc a nmuloc,dekcap elpmaS ezis : lVf1
egnirys-orciM - 1~1 yticapaC
fo xawobraC 20 M no brosomorhC .PHW
C-3 STNEGAER
evitatitnauQ stluser era deniatbo yb using elbatius
cinortcele rotargetni and aera noitazilamron eruP sdnuopmoc rof noitarbilac dluohs edulcni
dohtem hcihw sevig tcerid noitartnecnoc fo hcae
,etatecalyxeholcyc lyhteM ,enonaxeholcyC -4
tnenopmoc gnola htiw eht ,margotamorhc ,aera lyhteM ,enonaxeholcyC lonaxeholcyC fo a ytirup
noitneter ,emit .cte
ton less than 99 .tnecrep
C-2 APPARATUS C-4 PROCEDURE
Gas Chromatograph - Any tnemurtsni gnivah a eraperP citehtnys erutxim fo lonaxeholcyc and -per
negordyh emalf noitazinoi rotceted that yam eb evitatneser seitirupmi no a mass tnecrep basis. teS
detarepo at eht noitidnoc nevig :woleb
eht data no rotargetni rof aera noitazilamron
rotceteD : emalF noitazinoi .dohtem
nmuloC : sselniatS leets
tcejnI 1 lu, fo eht gnitluser noitulos otni eht
htgneL : 2 erteM hpargotamorhC and teg noituloser fo all eht -retni
.D.I mm3 detse skaep fo ytirupmi .erutxim At eht dne fo nur
yranoitatS : %51 xawobraC 20 M no pots eht .rotargetni ehT retnirp lliw tnirp eht aera
esahp brosomorhC PHW 001/08 fo hcae .tnenopmoc
mass tnecrep Mesh
C-5 NOITALUCLAC
erutarepmeT
ehT rotargetni yllacitamotua setaluclac eht
noitcejnI 230°C
tnuoma fo hcae laudividni tnenopmoc as :swollof
rotceteD : 230°C
OOlx,A
nmuloC 110°C tnecreP x =
aerA( fo all )skaep
reirraC saG : negortiN
erehw
wolF etar : 20 nim/lm
A, = aera fo tnenopmoc .x
IS 14375 : 1996
ANNEX D
(Clause 6)
SAMPLING OF CYCLOHEXANONE
)a gnilpmaS elttob ro ,nac rof taking samples
D-l GENERAL REQUIREMENTS
morf suoirav shtped fo egral tanks; and
nI ,gniward ,gniraperp gnirots and handling
D-1.0 )b gnilpmaS .ebut
tset samples, eht gniwollof snoituacerp and -cerid
snoit shall eb .devresbo 1.2-D Sampling Bottle or Can
tI stsisnoc fo dethgiew elttob ro latem reniatnoc
1.l-D selpmaS shall ton eb nekat ni an desopxe
htiw elbavomer reppots ro oJpot hcihw is dehcatta
.ecalp
a thgil niahc ees( .giF .)1 ehT elttob ro nac is
2.1-D ehT sampling tnemurtsni shall eb naelc and denetsaf ot a elbatius .elop roF taking a ,elpmas ti
yrd and shall eb edam fo wol ro decuder spark is derewol ni eht tank ot eht deriuqer ,htped and eht
gnitareneg .lairetam reppots ro pot is devomer yb snaem fo eht niahc rof
gnillif eht .reniatnoc
3.l-D ehT samples, eht lairetam gnieb ,delpmas
eht sampling tnemurtsni and eht sreniatnoc rof 2.2-D Sampling Tube
samples shall eb detcetorp morf suoititnevda -noc
tI is edam fo latem ro kciht glass and is tuoba 20 ot
.noitanimat
40 mm ni retemaid and 400 ot 800 mm ni htgnel ees(
4.l-D oT draw a evitatneserper ,elpmas eht -noc .giF .)2 ehT sdne era lacinoc and hcaer 5 ot 10 mm
stnet fo hcae reniatnoc detceles rof sampling shall retemaid at eht tips. gnildnaH is detatilicaf yb owt
eb dexim as ylhguoroht as elbissop yb shaking ro rings at eht reppu .dne roF taking a ,elpmas eht
gnirrits ro ,htob ro yb ,gnillor os as ot gnirb all apparatus is tsrif l+esolc at eht pot htiw eht bmuht
snoitrop otni mrofinu .noitubirtsid ro a reppots and derewol litnu eht derised htped is
.dehcaer tI is neht denepo rof a trohs emit ot timda
5.l-D ehT samples shall eb decalp ni ,elbatius
eht lairetam and yllanif desolc and .nwardhtiw
,naelc yrd and thgitria glass sreniatnoc ylbareferp fo
rebma ro eulb .ruoloc 1.2.2-D roF small ,sreniatnoc eht ezis fo eht -mits
gnilp ebut yam eb deretla .ylbatius
ehT elpmas sreniatnoc shall foeb hcus a ezis
D-l.6
that yeht era ,tsomla tub ton ,yletelpmoc dellif yb 3-D ELACS FO GNILPMAS
eht .elpmas
1.3-D toL
7.l-D rebbuR sreppots ro noitisopmoc skroc shall nI ,tnemngisnoc~yna all eht sreniatnoc fo eht emas
ton eb desu rof gnisolc eht elpmas .selttob ezis and drawn morf emas hctab fo erutcafunam
shall etutitsnoc a .tol
8.l-D gnilaeS xaw ro rehto citsalp ,lairetam fi ,desu
shall eb deilppa ni hcus a yaw that ti seod ton 2.3-D stseT shall eb detcudnoc no hcae tol
etanimatnoc eht elpmas nehw eht selttob era yletarapes rof gniniatrecsa eht ytimrofnoc ot eht
.denepo stnemeriuqer fo this .noitacificeps ehT rebmun fo
sreniatnoc ot eb nesohc at modnar morf eht tol rof
9.l-D hcaE elpmas reniatnoc shall eb detcetorp yb this esoprup shall dneped no eht ezis fo eht tol and
revoc fo lio foorp ,repap latem ,liof esocsiv ro rehto
shall eb ni ecnadrocca loc~htiw 1 and 2 fo elbaT 2.
elbatius suoivrepmi lairetam revo eht reppots ot
peek yawa erutsiom and dust morf eht htuom fo eht
elttob and ot tcetorp ti elihw gnieb .deldnah elbaT 2
Scale of Sampling
01.1-D hcaE elpmas reniatnoc shall eb delaes -ria
Number of Contuiners Number of Containers
thgit htiw a elbatius reppots retfa gnillif and in the Lot lo be Selected
dekram htiw lluf sliated fo sampling, hcus as eht
etad ,gnilpmasfo eht raey fo ,erutcafunam eht hctab (1) (2)
up ot
,rebmun eht eman fo eht ,relpmas .cte ralucitraP 25 3
erac shall eb nekat ot erusne that gnilaes sdohtem 26to1f.M 4
101 to 150 5
od ton etanimatnoc eht .elpmas
151andabove I
2-D GNILPMAS TNEMURTSNI D-3.3 The sreniatnoc shall eb detceles morf eht tol
at modnar and ni redro ot erusne eht ssenmodnar
0.2-D ehT gniwollof smrof fo sampling -urtsni fo ,noitceles eht dohtem nevig ni SI 4905 : 1968, yam
stnem yam eb :desu eb .dewollof
4
SI 14375 : 1996
&_
TO 10 mm 0
mm0
6
.GIF 2
SAMPLING TUBE
1 000 .lm ehT etisopmoc tset elpmas shall eb
dedivid otni eerht lauqe parts, eno rof eht -rup
,resahc rehtona rof eht reilppus and eht driht ot eb
desu as a eerefer .elpmas
3.4-D ehT parts fo eht etisopmoc tset ,elpmas -bo
.GIF 1 GNILPMAS ELTTOB CAN deniat gnidrocca ot ,2.4-D shall eb derrefsnart ot
OR
etarapes sreniatnoc and shall eb delaes and dekram
4-D NOITARAPERP FO TSET SELPMAS
htiw lluf noitacifitnedi sralucitrap nevig ni .01.1-D
1.4-D morF hcae fo eht sreniatnoc detceles -drocca
4.4-D ehT eerefer tset elpmas shall raeb eht seals
gni ot 2.3-D and ,3.3-D small snoitrop fo eht
fo htob eht resahcrup and eht .reilppus shall eb
lairetam shall eb drawn htiw eht pleh fo eht sam- It
tpek at a ecalp deerga ot neewteb eht resahcrup and
gnilp tnemurtsni ees( )2-D morf lareves snoitisop
eht reilppus ot eb desu ni eht esac fo yna etupsid
at eht ,reppu elddim and mottob .sreyal esehT
neewteb eht .owt
snoitrop shall eb dexim rehtegot os as ot dleiy a
ytitnauq fo lairetam ton less than 1 000 lm -erper 5-D AIRETIRC FOR YTIMROFNOC
evitatnes fo that .reniatnoc
1.5-D ehT tol shall eb deralced as gnimrofnoc ot
2.4-D morF hcae fo eseht laudividni samples, an eht stnemeriuqer fo this noitacificeps fi eht -moc
lauqe ytitnauq fo lairetam shall eb nekat and dexim etisop elpmas smrofnoc ot all eht deificeps -eriuqer
ylhguoroht ot mrof a etisopmoc ,elpmas fo tuoba .stnem
