Introduction to metal-nanoparticle plasmonics

295 Pages·2013·19.312 MB·English

by  Bryant, Garnett W., Pelton, Matthew

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Introduction to
Metal-Nanoparticle
Plasmonics
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Introduction to
Metal-Nanoparticle
Plasmonics
Matthew Pelton
ArgonneNationalLaboratory,Argonne,Illinois,USA
Garnett Bryant
NationalInstituteofStandardsandTechnology,Gaithersburg,
Maryland,USA
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Coverdesign:JohnWiley&Sons,Inc.
Coverillustration:CourtesyofGarnettBryant
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PublishedsimultaneouslyinCanada.
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LibraryofCongressCataloging-in-PublicationData:
Pelton,Matthew,1975–
Introductiontometal-nanoparticleplasmonics/MatthewPelton,GarnettBryant.
pagescm
Includesbibliographicalreferencesandindex.
ISBN978-1-118-06040-7(cloth)
1.Plasmons(Physics) 2.Metalpowders–Opticalproperties. 3.Nanoparticles–Electric
properties. I.Bryant,GarnettW. II.Title.
QC176.8.P55P4502013
560.4(cid:3)4–dc23
2012039993
PrintedintheUnitedStatesofAmerica
10 9 8 7 6 5 4 3 2 1
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ToE´va,
forallhersupport
andto
Virginia,Sean,andEric
fortheirpatience,
understanding,and
encouragement
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Contents
Acknowledgments ix
Introduction xi
I.1 WhyAlltheExcitement? xi
I.2 HistoricalPerspective xiv
I.3 BookOutline xvii
1 Modeling:UnderstandingMetal-NanoparticlePlasmons 1
1.1 ClassicalPicture:SolutionsofMaxwell’sEquations 2
1.2 DiscretePlasmonResonancesinParticles 13
1.3 OverviewofNumericalMethods 25
1.4 AModelSystem:GoldNanorods 31
1.5 Size-DependentEffectsinSmallParticles 39
References 46
2 Making:SynthesisandFabricationofMetalNanoparticles 51
2.1 Top-Down:Lithography 52
2.2 Bottom-Up:ColloidalSynthesis 67
2.3 Self-AssemblyandHybridMethods 76
2.4 ChemicalAssembly 86
References 92
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viii Contents
3 Measuring:CharacterizationofPlasmonsinMetalNanoparticles 97
3.1 EnsembleOpticalMeasurements 97
3.2 Single-ParticleOpticalMeasurements 102
3.3 ElectronMicroscopy 125
References 132
4 CoupledPlasmonsinMetalNanoparticles 135
4.1 PairsofMetalNanoparticles 136
4.2 UnderstandingComplexNanostructuresUsingCoupledPlasmons 149
References 161
5 NonlinearOpticalResponseofMetalNanoparticles 165
5.1 ReviewofOpticalNonlinearities 166
5.2 Time-ResolvedSpectroscopy 170
5.3 HarmonicGeneration 187
References 191
6 CouplingPlasmonsinMetalNanoparticlestoEmitters 193
6.1 Plasmon-ModifiedEmission 193
6.2 Plasmon–EmitterInteractionsBeyondEmissionEnhancement 210
References 225
7 SomePotentialApplicationsofPlasmonicMetalNanoparticles 229
7.1 Refractive-IndexSensingandMolecularDetection 229
7.2 Surface-EnhancedRamanScattering 233
7.3 Near-FieldMicroscopy,Photolithography,andDataStorage 239
7.4 PhotodetectorsandSolarCells 242
7.5 OpticalTweezers 249
7.6 OpticalMetamaterials 254
References 266
Index 271