Interactions of nanomaterials with emerging environmental contaminants

239 Pages·2013·4.541 MB·English

by  Doong, Ruey-an, Kim, Hyunook, Sharma, Virender K

Interactions of Nanomaterials
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In Interactions of Nanomaterials with Emerging Environmental Contaminants; Doong, R., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2013.
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In Interactions of Nanomaterials with Emerging Environmental Contaminants; Doong, R., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2013.
1150
ACS SYMPOSIUM SERIES
Interactions of Nanomaterials
with Emerging Environmental
Contaminants
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w Ruey-an Doong, Editor
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1/ Virender K. Sharma, Editor
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AmericanChemicalSociety,Washington,DC
DistributedinprintbyOxfordUniversityPress
In Interactions of Nanomaterials with Emerging Environmental Contaminants; Doong, R., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2013.
LibraryofCongressCataloging-in-PublicationData
Interactionsofnanomaterialswithemergingenvironmentalcontaminants/Ruey-anDoong,
editor,NationalTsingHuaUniversity,Hsinchu,Taiwan,VirenderK.Sharma,editor,Florida
InstituteofTechnology,Melbourne,Florida,UnitedStates,HyunookKim,
editor,UniversityofSeoul,Seoul,RepublicofKorea;sponsoredbytheACSDivisionof
EnvironmentalChemistry.
1
0 pagescm-- (ACSsymposiumseries;1150)
0
w Includesbibliographicalreferencesandindex.
50.f ISBN978-0-8412-2916-7(alk.paper)
1
1 1. Pollutioncontrolequipment--Materials--Congresses.2. Catalysts--Congresses.3.
13- Nanostructuredmaterials--Industrialapplications--Congresses.4. Nanostructured
0
2 materials--Environmentalaspects--Congresses.5. Pollution--Congresses. I.Doong,
k-
b Ruey-an.II.Sharma,VirenderK.III.Kim,Hyunook.IV.AmericanChemicalSociety.
1/
2 DivisionofEnvironmentalChemistry.
0
0.1 TD192.3.I582013
doi: 1 620.1’159--dc23 2013039591
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In Interactions of Nanomaterials with Emerging Environmental Contaminants; Doong, R., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2013.
Foreword
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In Interactions of Nanomaterials with Emerging Environmental Contaminants; Doong, R., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2013.
Preface
Emerging environmental contaminants are newly identified or previously
unrecognized pollutants, which primarily include human and veterinary
pharmaceuticals and personal-care products, surfactants, plasticizers, flame
retardants, metals and metalloids, various industrial additives, pesticides, and
1 pesticidemetabolites. Theuseofnovelnanomaterialswithuniquecharacteristics
0
0
pr hasbeendemonstratedtoincreasetheremovalefficiencyofemergingpollutants,
0.
5 whichprovidesapromisingstrategytocontrolthedistributionofenvironmental
1
1
3- contaminants. In addition, nanomaterials also can serve as ideal platforms for
1
20 precise and accurate detection and sensing of emerging contaminants in the
bk- environmentandbiologicalfluids;thisisbecauseoftheirnovelcharacteristicson
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2 opticalandelectrochemicalproperties. Theinteractiveresearchofnanomaterials
0
1
0. with emerging environmental contaminants will improve our understanding of
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oi: theimplicationandapplicationofnanomaterialsintheenvironment.
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3 | This book is derived from the symposium “Interactions of Nanomaterials
01 withEmergingEnvironmentalContaminants”atthe244thACSNationalMeeting
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9, in Philadelphia during the fall of 2012 sponsored by the American Chemical
2
er Society (ACS) Division of Environmental Chemistry. Many topics addressing
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cto issues of interaction of emerging environmental pollutants with nanomaterials
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b): (including physical, photochemical, and biological interactions) were presented
e inthissymposium,andtheyconstitutethemaincontentofthisbook.
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e ( This book contains 12 peer-reviewed chapters that cover various aspects of
Dat interaction of various nanomaterials with environmental contaminants. These
on chapterscanbeorganizedintotwomajorsections: (I)interactionofnanomaterials
cati with biomolecules for biosensing and detection of contaminants (Chapter 1-4)
ubli and (II) interaction of nanomaterials with contaminants to enhance the removal
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efficiency and rate of emerging pollutants (Chapter 5-12). Chapter 1 by Ren,
Zang, Qie, and Baker provides an overview of the adjuvant effect of emerging
nanomaterials. The nanoparticles can serve as drug delivery to deliver antigens
to species targets. In contrast, ambient nanoparticles exhibit adverse effect on
human and ecological health. To address the accurate and precise detection of
environmental contaminants in the environment (as well as in the human body),
Chapter 2 and Chapter 3 have developed photoluminescent gold nanomaterials
— including gold nanoparticles and gold nanodots — for the monitoring and
detection of metal ions, proteins, and bacteria in an aquatic ecosystem. In
Chapter 2, Unnikrishnan and Huang have synthesized luminescent core-shell
Au nanodots using different kinds of capping ligands (including alkanethiols,
proteins, DNA, thiol derived carbohydrates, and aptamers) as the shell layer for
detection and determination of mercury ions, proteins, and E. coli. Chang and
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In Interactions of Nanomaterials with Emerging Environmental Contaminants; Doong, R., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2013.
histeam(Chapter3)havedevelopedseveralfunctionalAunanoparticlesandAu
nanodot-basedsensorsthatallowthesensitiveandselectivedetectionofmercury,
lead, and copper ions through analytes induced changes in colors, absorption,
and fluorescence. In addition, a biosensing system (AlGaN/GaN high electron
mobility transistors immobilized with antibodies) is developed by Wang and his
team (Chapter 4) to effectively detect a short peptide only containing 20 amino
acids,whichopensadoorforinvestigationintonanomaterialswithbiomolecules.
Theapplicationsofnanomaterialsforvariousreactions(includingadsorption,
photocatalytic degradation, and reductive dechlorination) are also addressed.
Huang,Padhye,andWang(Chapter5)describethegenerationofN-nitrosamines
fromtransformationofaminescatalyzedbyactivatedcarbons. Thisinteractionis
important because activated carbon and amine are often used in water treatment
plants. In Chapter 6, Du and Jing explore the dynamic adsorption process of
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0 propranolol at the TiO /water interface on the molecular level. In addition to
pr 2
50. adsorption behavior, Hung and his colleagues (Chapter 7) combine TiO2 and
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1 carbon nanotubes to adsorb and look at the photocatalytic decomposition of
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1 bisphenol A, which is an endocrine disrupting chemical widely existing in the
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1 pollutants in the environment. Ren, Han, Al Anazi, Nadagouda, and Dionysiou
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doi: 1 f(oCrhaepntevriro8n)mednistaclussremtheediaatpiopnlica—tionincolfudidnigfferweantterirotrne-abtamseendt,nagnrooumnadtweraiatelsr
13 | remediation, and soil decontamination. Ferrate, ferrites, and TiO2-composite
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9, 2 magnetic iron oxides are used for the removal of contaminants of emerging
er 2 pollutants. Inadditiontoironoxidecatalysts,zerovalentmetalsarealsocommon
b nanomaterials widely used for reduction of emerging pollutants. Su, Tso, Peng,
o
Oct andShih(Chapter9)haveusednanoscalezerovalentiron(nZVI)andbimetallic
b): Pd/Fe as the dual functional tools for adsorption and reduction of aromatic
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W contaminants (including decabrominated diphenyl ether, hexachlorobenzene,
ate ( penrachlorophenol,andCongored). Thecombinationofbiologicalorsequential
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n Fenton treatment on the mineralization of some emerging contaminants is also
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ati evaluated in this chapter. In Chapter 10, McPherson, Goltz, and Agrawal
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to nZVI decreases particle agglomeration and reduces particle size — resulting
in the increase in reactivity and transport in porous media. The modification of
nZVI with Pd and Ni for the enhancement of reactivity is also summarized and
discussed. In addition, three field studies using Pd-nZVI for the remediation of
chlorinated compounds in groundwater are introduced. Sharma, Siskova, and
Zboril (Chapter 11) review the recent development of nanoscale zerovalent iron
andmagneticbimetallicFe/Agnanoparticleswithcore-shellstructures. Theyalso
show the usefulness of these nanomaterials on nutrient removal, transformation
of halogenated aromatic contaminants, and antimicrobial activity. In addition to
zerovalentiron,LeeandDoong(Chapter12)havedemonstratedthefeasibilityof
usinganotherenvironmentallyfriendlymetaltoremovechlorinatedcompounds.
In this chapter, the authors review and discuss the reductive dechlorination of
chlorinated hydrocarbons and emerging pollutants by zerovalent silicon and
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In Interactions of Nanomaterials with Emerging Environmental Contaminants; Doong, R., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2013.
bimetallic Fe/Si and Ni/Si. More importantly, they demonstrate the synergistic
effectofnickelionsandpolyethyleneglycolonthedechlorinationrate.
The understanding of interaction of emerging contaminant with various
nanomaterialsisessentialtoexploringtheapplicationsofnanotechnologyinthe
environment. We hope that this collection will benefit graduate students who
areengagedinresearchanddevelopmentintheadvancementofnanotechnology
and environmental science and technology. We wish to thank Anne Brenner
and Timothy Marney of the editorial department of ACS for their assistance in
preparingthisvolumeandforkeepingusonschedule.
Ruey-anDoong
DepartmentofBiomedicalEngineeringandEnvironmentalSciences
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doi: 1 CFlhoermidiastIrnystDiteuptearotmfTeencthnology
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In Interactions of Nanomaterials with Emerging Environmental Contaminants; Doong, R., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2013.
Editors’ Biographies
Ruey-an Doong
Ruey-anDoongreceivedhisPh.D.inEnvironmentalEngineeringatNational
TaiwanUniversityin1992. HeisafullprofessorintheDepartmentofBiomedical
Engineering and Environmental Sciences at National Tsing Hua University in
Taiwan. Currently, Prof. Doong is the Dean of the College of Nuclear Science
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0 at National Tsing Hua University. He is also serving as an editorial member of
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15 of Biosensors and Bioelectronics, and Journal of Environmental Chemical
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3- Engineering. He has authored more than 200 journal articles, book chapters,
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2 Chemistry at the University of Miami after graduating from the Indian Institute
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2 of Technology in New Delhi, India with a Master’s degree in Technology. He
ber is currently a director of the Center of Ferrate Excellence and a professor of
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Oct chemistry at Florida Institute of Technology. He was a visiting research scholar
b): at Stanford University under the advisory of Professor Ed Solomon and won
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e ( Outstanding Chemist Award in 2008. He is highly active in pursuing chemistry
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Synthesis, Properties, and Applications in Water and Wastewater Treatment and
Sustainable Nanotechnology and the Environment: Advances and Achievements
(publishedbyOxfordUniversityPress).
Hyunook Kim
HyunookKimisaProfessorofEnvironmentalEngineeringattheUniversity
ofSeoulinKoreaandtheDirectoroftheR&DCenterofCoreTechnologiesfor
WaterTreatment. ProfessorKimearnedhisB.S.degreeinEnvironmentalScience
from Yonsei University in Korea in 1994, an M.S. degree in Environmental
Engineering from Johns Hopkins University in 1997, and a Ph.D. from The
UniversityofMarylandatCollegeParkin2000. Beforehejoinedthefacultyat
©2013AmericanChemicalSociety
In Interactions of Nanomaterials with Emerging Environmental Contaminants; Doong, R., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2013.
the University of Seoul in 2002, he worked as Environmental Engineer for the
U.S.Dept. ofAgriculture(MD,USA).
Professor Kim’s research in the area of water pollution control includes a
numberofprojectsonprocesscontrolandtheoperationofwaterandwastewater
treatment plants. He is especially interested in monitoring and control of
contaminantsofemergingconcern. Hehaswrittennumerousjournalpapersand
conference presentations. He has served as Associate Editor of Chemosphere
since2007andasanEditorialBoardmemberofCriticalReviewinEnvironmental
ScienceandTechnologysince2012.
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In Interactions of Nanomaterials with Emerging Environmental Contaminants; Doong, R., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2013.