Table Of ContentELECTROSPUN AND NANOFIBROUS
MEMBRANES
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ELECTROSPUN
AND NANOFIBROUS
MEMBRANES
Principles and Applications
Editedby
A K
LI ARGARI
DepartmentofChemicalEngineering,AmirkabirUniversityofTechnology(TehranPolytechnic),Tehran,Iran
T M
AKESHI ATSUURA
DepartmentofChemicalandBiologicalEngineering,UniversityofOttawa,Ottawa,ON,Canada
M M A. S
OHAMMAD AHDI HIRAZI
MembraneIndustryDevelopmentInstitute,Tehran,Iran
Elsevier
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Contents
Contributors ix 8. Multiplenozzleelectrospray 63
9. High-throughputelectrospray 64
I 10. Electrosprayconfigurations 65
11. Thecomparisonofelectrosprayandothermethods
Principles intermsoffiberproduction 65
12. Applications 66
13. Patents 73
1. Principles of electrospinning 14. Conclusionsandfutureperspectives 73
and nanofiber membranes References 77
TAKESHIMATSUURAANDMOHAMMADMAHDIA.SHIRAZI 4. Gas-assisted electrospinning and
electroblowing
1. Introduction 3
2. Electrospinningtechnology 9 MAREKPOKORNY´,LENKABARDONˇOVA´,ADE(cid:1)LAKOTZIANOVA´,
3. Outlinesofthisbook 19 ANDVLADIM´IRVELEBNY´
References 19
1. Introduction 82
Furtherreading 25
2. Inputandsetupparametersoftheelectroblowing
2. Melt electrospinning for membrane process 83
3. Regulatedprocessparametersintheelectroblowing
fabrication
method 89
MUHAMMADAMIRULISLAM,SEYEDABOLHASSANHOSSEINI, 4. Propertiesoffibrousstructuresproducedby
LALEHSHAMAEI,SADEGHAGHAPOURAKTIJ,AND
electroblowing 91
MOHTADASADRZADEH
5. Conclusionsandfutureperspectives 99
1. Introduction 27 References 100
2. Meltelectrospinning 28
5. Coaxial electrospinning
3. Influentialfactorsonmeltelectrospinning 31
4. Progressinmeltelectrospinningdevices 40 MAHSAMOSTOFIZADEH,MICAL.PITCHER,ANDAMIRSHEIKHI
5. Fabricatingporousmembranesbymelt
1. Introduction 105
electrospinning 41
2. Engineeringfiberstructuresviacoaxial
6. Conclusions 46
electrospinning 106
References 46
3. Coaxialelectrospinningprocessandparameters 109
3. Electrospraying for membrane fabrication 4. Applicationsofcoaxialelectrospinning 114
5. Conclusionsandfutureperspectives 121
SEYEDEHSHADIHOSSEINIANDAFSANEHVALIPOURI
References 123
1. Introduction 53
6. Bubble electrospinning: Mass production of
2. Backgroundofelectrospray 54
3. Electrosprayprocessandbasicprinciples 55 nanomaterials
4. Governingequations 56
XIAO-XIALI,ZHILIU,ANDJI-HUANHE
5. Dimensionlessnumbers 57
6. Electrosprayingmodes 58 1. Introduction 128
7. Effectiveparameters 61 2. Bubbleelectrospinningtechnology 128
v
vi
Contents
3. Thedeviceofbubbleelectrospinning 133 Acknowledgment 260
4. Fibermorphologyofbubbleelectrospinning 136 References 260
5. Conclusionsandfutureperspectives 141
References 141
10. Nonelectro nanofiber spinning
techniques
7. Needleless electrospinning
ALIKILIC,SULESELCUK,ALITOPTAS,
MONIREHKOUHI,MINAMOBASHERI,AND
ANDAYBENIZSEYHAN
AFSANEHVALIPOURI
1. Introduction 267
1. Introduction 145
2. Solutionblowing(SB-spin) 269
2. Principleofneedlelesselectrospinning 146
3. Centrifugalspinning(CS) 273
3. Materialssuitableforapplicationinneedleless
4. Meltblowing 277
electrospinning 146
4. Deviceset-upinneedlelesselectrospinning 147 5. Othernonelectronanofiber-spinning
techniques 279
5. Formationofcore-shellnanofibersbyneedleless
6. Hybridnanofibermanufacturingtechniques 283
electrospinning 158
6. Applicationofneedlelesselectrospun 7. Conclusionsandfutureperspectives 284
References 285
membranes 160
7. Recentpatentsonneedlelesselectrospinning 163
8. Challengesandfutureperspectives 166 11. Characterization of nanofibers and
9. Conclusions 167
nanofiber membranes
References 167
MORTEZAAFSARI,HOKYONGSHON,ANDLEONARDD.TIJING
8. Organic and inorganic electrospun
1. Introduction 296
nanofibers
2. Characterizationofnanofibersandnanofiber
MOHAMMADHASSANKANANI-JAZIANDSOMAYEAKBARI membranes 296
3. Physicalandmorphologicalcharacterization 297
1. Introduction 173
4. Mechanicalcharacterizationofthenanofibers 308
2. Fabricationmethodsoforganic/inorganic
5. Chemicalcharacterizationofnanofibers 311
nanofibers 175
6. Thermalcharacterization 313
3. Applicationsfororganic/inorganicnanofibers 181
7. Electricalanddielectricbehaviormeasurement 315
4. Patentanalysis 188
8. Conclusionandfutureperspectives 317
5. Characterizationoforganic/inorganicelectrospun
References 318
fibers 189
6. Conclusionsandfuturetrends 197
II
References 197
9. Scale-up strategies for electrospunnanofiber Applications
production
12. Electrospun membranes for microfiltration
YANBOLIU,MINGHAO,CONGZHOU,BOYANG,SHANJIANG,
JUANHUANG,ZHIJUNCHEN,YONGLIU,AND BIHTERZEYTUNCU,REYHANSENGUR-TASDEMIR,
SEERAMRAMAKRISHNA MEHMETEMINPASAOGLU,RECEPKAYA,TURKERTURKEN,
ANDISMAILKOYUNCU
1. Introduction 206
2. Categoriesofelectrospinningtechnologies 207 1. Introduction 325
3. Issuesinelectrospinningtechnology 225 2. ComparisonofconventionaltechniquesforMF
4. Strategiesforscale-upelectrospinning 227 fabricationwithelectrospinningtechnique 326
5. Progressinlarge-scaleelectrospinning 250 3. Modificationofelectrospunnanofibermembranes
6. Summary 260 formicrofiltration 328
vii
Contents
4. Applicationofelectrospunnanofibermembranes 7. Fundamentalsandapplicationsofnanofiber-
onmicrofiltration 330 embeddedcoalescingfiltration 419
5. Recentpatentsinmicrofiltrationapplication 8. Comparisonofelectrospunandphaseinversion
ofnanofibrousmembranes 339 membranesfortheseparationofoil-in-water
6. Conclusionsandfutureperspectives 342 emulsion 426
References 342 9. Foulingandcleaningoftheelectrospunmembranes
appliedforoil-in-waterseparation 426
10. Conclusionandfutureperspectives 427
13. ElectrospunmembranesforUF/NF/RO/FO/
References 427
PRO membranes and processes
LUKKATHUYAVANYOGARATHINAM,JUHANAJAAFAR, 16. Electrospun adsorptive membranes for
AHMADFAUZIISMAIL,PEISEANGOH,
ion adsorption
MOHDHAFIZDZARFANOTHMAN,MUKHLISA.RAHMAN,
ANDJEROMEPETER
MOHAMMADAMINALAEISHAHMIRZADIANDALIKARGARI
1. Introduction 347
1. Introduction 433
2. Pressure-drivenmembraneprocess 348
2. Conceptofadsorptivemembranes 434
3. Osmoticallydrivenmembraneprocesses 357
3. Electrospinningtechniques 436
4. Conclusionandfutureperspectives 360
4. Typesofelectrospunadsorptivemembranes 437
References 365
5. Polymertypesfornanofibermembranes 438
6. Modificationmethods 440
14. Electrospun and nanofibrous membranes 7. Electrospunfunctionalization 441
for membrane distillation 8. Inorganicelectrospunmembranes 444
9. Mixedmatrixmembranes 445
MOHAMMADAMINALAEISHAHMIRZADI,KAMRANJALALI, 10. Currentchallengesandfuturepotential 449
ANDALIKARGARI
References 449
1. Introduction 372
2. Electrospinning 375 17. Electrospun ion-exchange membranes
3. Otherfabricationmethods 379
SHAOLINGZHANGANDHIDETOSHIMATSUMOTO
4. Characterizationofelectrospunnanofibrous
membranes(ENMs)forMD 380 1. Introduction 455
5. ModificationofENMsforMD 382 2. Fundamentalaspectsofion-exchangenanofibers 456
6. DifferenttypesofENMs 392 3. Applicationofion-exchangenanofibers 459
7. PatentsonENMsforMDapplication 395 4. Summaryandoutlook 464
8. Futureperspectiveandconcludingremarks 395 References 466
References 400
18. Nanospun membranes developed by
15. Nanofibers for oil-water separation and electrospinning techniques for drug delivery
coalescing filtration applications
FATMAYALCINKAYA,AYSEGULGUNDUZ,EVRENBOYRAZ, MAHADEVAPPAY.KARIDURAGANAVAR,
ANDMAREKBRYJAK GEETHAB.HEGGANNAVAR,NANDINIA.PATTANASHETTI,
NEETAU.DONNIMATH,ANDGEOFFREYR.MITCHELL
1. Introduction 410
2. Fundamentalsofsurfacescience 410 1. Introduction 472
3. Surfacemodification 413 2. Electrospunfibers 473
4. Preparationofnanofibermembranes 415 3. Drugloadinganddrugreleasefromelectrospun
5. Membranestability 417 nanofibers 475
6. Casestudiesonseparationoftheoil-water 4. Materials 479
emulsion 418 5. Applications 481
viii
Contents
6. Conclusionsandfutureprospective 493 5. Conclusionandfutureperspectives 571
Acknowledgments 493 References 572
References 493
Furtherreading 499 22. Electrospun membranes for air filtration
F.RUSSO,S.SANTORO,R.CASTRO-MUN˜OZ,F.GALIANO,AND
19. Antimicrobial electrospun membranes
A.FIGOLI
PAYAMZAHEDI,ALIREZAKHATIBI,ANDMAHSHID
1. Introduction 577
FALLAH-DARREHCHI
2. Mechanismoffiltration 580
1. Introduction 501 3. Performanceevaluation 583
2. Mainapplicationsofantimicrobialnanofibrous 4. Electrospunnanofibermaterialsforairfiltration 585
membranes 502 5. Electrospunnanofiberconfigurations 589
3. Antimicrobialagentsandtheirusageinwound 6. Applicationsforairfiltration 589
dressings 506 7. Conclusionsandfutureperspectives 595
4. Conclusionandfutureperspectives 515 References 596
References 516
23. Smart and novel nanofiber membranes
20. Electrospun membranes for batteries
F.GALIANO,S.SANTORO,R.CASTRO-MUN˜OZ,F.RUSSO,AND
PRIYESHWAGH A.FIGOLI
1. Introduction 521 1. Introduction 603
2. ElectrospunmembranesforthefabricationofLIBs 523 2. Janusmembranes 605
3. Electrospunmembranesforthefabricationof 3. Nanofibermembranesinregenerativemedicine 607
next-generationbatteries 538 4. Nanofibermembraneswithnanonets/spiderweb 610
4. Researchandcommercializationeffortsacrossthe 5. Nanofibroussensitivemembranes 613
world 538 6. Nanofibermembranesfortheencapsulationof
5. Challengesandperspectives 539 bioactivecompounds 616
References 545 7. Conclusionandfutureperspectives 618
References 619
21. Electrospun membranes for fuel cell
24. Future perspectives and market of the
technology
electrospun and nanofibrous membranes
HAZLINAJUNOH,JUHANAJAAFAR,
MOHDHAFIZDZARFANOTHMAN, TAKESHIMATSUURAANDMOHAMMADMAHDIA.SHIRAZI
NIKABDULHADIMOHDNORDIN,AHMADFAUZIISMAIL,
MUKHLISA.RAHMAN,FARHANAAZIZ,AND 1. Introduction 625
NORHANIZAYUSOF 2. Progressinresearchandtechnology 626
3. Progressinthemarket 629
1. Introduction 555
4. Futureperspective 630
2. Electrospinningsetupandprocess 557
References 632
3. Operatingparametersforelectrospinning 565
4. Electrospunmembranesforfuelcell
Index 637
applications 567
Contributors
MortezaAfsari CentreforTechnologyinWaterand NeetaU. Donnimath KarnatakaInstituteforDNA
Wastewater, School of Civil and Environmental Research,Dharwad,India
Engineering, University of Technology Sydney Mahshid Fallah-Darrehchi Nano-Biopolymers
(UTS),Ultimo,NSW,Australia ResearchLaboratory,SchoolofChemicalEngineer-
SadeghAghapourAktij DepartmentofMechanical ing,CollegeofEngineering,UniversityofTehran,
Engineering, Advanced Water Research Lab Tehran,Iran
(AWRL), University of Alberta, Edmonton, AB, A.Figoli InstituteonMembraneTechnology(CNR-
Canada ITM),Rende,Cosenza,Italy
Somaye Akbari Textile Engineering Department, F. Galiano Institute on Membrane Technology
SchoolofMaterialsandAdvancedProcessesEngi- (CNR-ITM),Rende,Cosenza,Italy
neering,AmirkabirUniversityofTechnology(Teh-
Pei Sean Goh Advanced Membrane Technology
ranPolytechnic),Tehran,Iran
Research Centre (AMTEC), School of Chemical
Mohammad Amin Alaei Shahmirzadi Membrane and Energy Engineering, Faculty of Engineering,
Processes Research Laboratory (MPRL), Depart- Universiti Teknologi Malaysia, Johor Bahru,
mentofChemicalEngineering,AmirkabirUniver- Malaysia
sity of Technology (Tehran Polytechnic), Tehran,
Aysegul Gunduz Institute for Nanomaterials,
Iran
AdvancedTechnologiesandInnovation,Technical
Farhana Aziz Advanced Membrane Technology UniversityofLiberec,Liberec,CzechRepublic
Research Centre (AMTEC), Universiti Teknologi
Ming Hao School of Textile Science and Engineer-
Malaysia, Skudai, Malaysia; Faculty of Chemical
ing, Wuhan Textile University, Wuhan; School of
and Energy Engineering, University Technology
TextileScienceandEngineering,TiangongUniver-
Malaysia,Skudai,Malaysia
sity,Tianjin,China
LenkaBardonˇova´ Contiproa.s.,R&DDepartment,
Doln´ı Dobrou(cid:1)c; Nanotechnology Centre, CEET, Ji-Huan He National Engineering Laboratory for
VSB – Technical University of Ostrava, Ostrava, ModernSilk,CollegeofTextileandClothingEngi-
neering, Soochow University, Suzhou; School of
CzechRepublic
Science,Xi’anUniversityofArchitectureandTech-
Evren Boyraz Faculty of Mechatronics, Technical nology,Xi’an,China
UniversityofLiberec,Liberec,CzechRepublic
GeethaB.Heggannavar DepartmentofChemistry,
MarekBryjak FacultyofChemistry,WroclawUni- KarnatakUniversity,Dharwad,India
versity of Science and Technology, Wroclaw,
Seyed Abolhassan Hosseini Department of
Poland
Mechanical Engineering, Advanced Water
R.Castro-Mun˜oz TecnologicodeMonterrey,Cam- Research Lab (AWRL), University of Alberta,
pus Toluca, Toluca de Lerdo, M(cid:3)exico; Faculty of Edmonton,AB,Canada
Chemistry, Department of Process Engineering
Seyedeh Shadi Hosseini Department of Mechani-
and Chemical Technology, Gdansk University of
calEngineering,IsfahanUniversityofTechnology,
Technology,Gdansk,Poland
Isfahan,Iran
Zhijun Chen School of Textile Science and Engi-
JuanHuang SchoolofTextileScienceandEngineer-
neering,WuhanTextileUniversity,Wuhan,China
ing,WuhanTextileUniversity,Wuhan,China
ix
