Catalysis by Acids and Bases

461 Pages·1985·16.75 MB·English

by  B. Imelik

Studies in Surface Science and Catalysis 20
CATALYSIS BY ACIDS AND BASES
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Studies in Surface Science and Catalysis 20
CATALYSIS BY ACIDS
AND BASES
Proceedings of an International Symposium
- -
organized by the lnstitut de Recherches sur la Catalyse CNRS Villeurbanne
and sponsored by the Centre National de la Recherche Scientifique,
Villeurbanne (Lyon), September 25-27,1984
Editors
B. Imelik, C. Naccache, G. Coudurier, Y. Ben Taarit and J.C. Vedrine
lnstitut de Recherches sur la Catalyse, CNRS, 69626 Villeurbanne, France
ELSEVIER Amsterdam - Oxford - New York - Tokyo 1985
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V
CONTENTS
Studies in Surface Science and Catalysis ............................ IX
Foreword ............................................................ XI
Pr~face........ ..................................................... XI11
Catalysis by solid bases and related subjects (K. Tanabe) ........... 1
A TPD, FT-IR and catalytic study on the interaction of methanol
with pure and KOH doped Ti02 anatase (G. Busca, P. Forzatti,
J.C. Lavalley and E. Tronconi) ...................................... 15
Acid and base strength of alumina-magnesia mixed oxides
(J.A. Lercher, Ch. Colombier, H. Vinek and H. Noller) ............... 25
Influence of the operating conditions on the morphology and
....
acidity of K2C03/y A1203 (X. Montagne, C. Durand and G. Mabilon) 33
Acidic reactions on some transition metal oxide systems
..........................................
(8. Grzybowska-Swierkosz). 45
Modification of the acidity and basicity of the surface oxide
catalysts (S. Malinowski) ........................................... 57
Basic molecular sieve catalysts/side-chain alkylation of toluene
by methanol (J.M. Garces, G.E. Vrieland, S.I. Bates, F.M. Scheidt).. . 67
Importance of the acid strength in heterogeneous catalysis
(D. Barthomeuf) ..................................................... 75
Structure and acidic properties of high silica faujasites (F. Maug6,
A. Auroux, J.C. Courcelle, Ph. Engelhard, P. Gallezot and
J. Grosmanginl ....................................................... 91
Acidity in zeolites (A.G. Ashton, S. Batmanian, D.M. Clark, J.Dwyer,
........................
F.R. Fitch, A. Hinchcliffe and F.J. Machado) 101
Acidic and basic properties of aluminas in relation to their
properties as catalysts and supports (H. Knozinger) ................. 111
Reactivity of isopropanol on K- and Cs-exchanged ZSM-5 and mordenite
.....
(J.B. Nagy, J.-P. Lange, A. Gourgue, P. Bodart and Z. Gabelica) 127
Quantitation and modification of catalytic sites in ZSM-5
(E.G. Derouane, L. Baltusis, R.M. Dessau and K.D. Schmitt) .......... 135
VI
Characterization of acidic properties of heteropoly compounds
in relation to heterogeneous catalysis (M. Misono) ................. 147
Heteropoly compounds : solid acids with guarded protons
......................................................
(J.B. Moffat) 157
Heteropolyacids as solid-acid catalysts (Y. Ono, M. Taguchi,
.....................................
Gerile, S. Suzuki and T. Baba) 167
New covalent boron (111)-molybdenum (VI) mixed 0x0 model compounds
as eligible hetero bimetallic catalysts for propylene epoxidation
(E. Tempesti, L. Giuffre, C. Mazzocchia and F. Di Renzo) ........... 177
Catalytic activities and selectivities of crystalline E-Zr(HP04)2
............................
(K. Segawa, Y. Kurusu and M. Kinoshita) 183
Calorimetric study of adsorption of ammonia at 420 K on bismuth
...................................
molybdate (2 : 1) (L. Stradella) 191
Skeletal isomerization of n-butene over modified boron phosphate
.............................
(B.P. Nilsen, M. Stoecker and T. Riis) 197
Catalytic application of hydrophobic properties of high- silica
zeolites. 11. Esterification of acetic acid with butanols
(S. Namba, Y. Wakushima, T. Shimizu, H. Masumoto and T. Yashima) ... 205
The mechanism of n-pentane transformation over solid superacids
........................................
A1 *03/A1 C1 (M. Marczews ki) 213
Factors affecting the deactivation of zeolites by coking
..................................................
(E. G. Derouane). 221
Valorisation des oliifines : oligom6risation catalysiie par le
...................
trifluorure de bore (C. Marty et Ph. Engelhard) 241
Upgrading of C4 cracking cuts with acid catalysts (B. Juguin,
...........................................
B. Torck and G. Martino) 253
Hydrocracking of n-heptane on Pt-HZSM-5. Effect of calcination and
.......
reduction conditions (G. Giannetto, G. Perot and M. Guisnet) 265
Transition ions exchanged zeolites as cracking catalysts (0. Cornet
...............................................
and A. Chambellan).. 273
VII
Characterization of acid catalysts by use of model reactions
....................................................
(14. Guisnet) 283
Application de la resonance magnetique nucleaire ?il 'etude de la
distribution et de l'acidite de l'eau de constitution des solides
.............................
(C. Doremieux-Morin et J. Fraissard). 299
Microcalorimetric characterization of acidity and basicity of
..............
various metallic oxides (A. Auroux and J.C. Vedrine) 311
Determination de l'acidite de catalyseurs solides en milieu
aqueux a l'aide d'un marqueur cinetique (R. Durand, P. Geneste,
...........................................
C. Moreau et S. Mseddi) 319
Degradation mechanism of 3-methyl-pentane on a supported superacid
catalyst studied by the 13C isotopic tracer technique
....................................
(F. Le Normand.and F. Fajula). 325
Relationship between catalytic activity and acid strength of LaHY
zeolites in cumene cracking and o-xylene isomerization
.............................
(She Li-Qin, Hung Su and Li Xuan-Wen) 335
Acid properties of a bidimensional zeolite (D. Plee, A. Schutz,
.....................................
G. Poncelet and J.J. Fripiat) 343
Thermal stability and acidity of A13+ cross linked smectites
....
(D. Tichit, F. Fajula,F. Figueras, J. Bousquet and C. Gueguen) 351
Mechanisms of the acid-catalyzed is omerizati on of paraffins
.......................................................
(F. Fajula) 361
Acidic catalysis and radical assistance (D. Brunel, H. Choukroun,
.....................................
A. Germain and A. Commeyras). 371
Alkylation of benzene with propene on benzyl sulfonic acid
siloxane catalysts (A.Saus, B. Limbacker, R. Brtills and R. Kunkel). 383
The conversion of dimethylether over Pt/H-ZSMS, A bifunctional
catalyzed reaction (C.W.R. Engelen, J.P. Wolthuizen and
................................................
J.H.C. Van Hooff) 391
Acid-catalyzed conversion of n-decane over high-silica faujasites
.....................
(P.A. Jacobs, J.A. Martens and H.K. Beyer).. 399
VIII
A new approach to the cracking of alkanes as a test reaction
..................
for solid acid catalysts (A. Corma and V. Forn6s) 409
Comparison of the reactions of ethylcyclohexane and 2-methyl heptane
on Pd/LaY zeolite (J. Weitkamp and S. Ernst) ....................... 419
Primary cracking modes of long chain paraffinic hydrocarbons in
open acid zeolites (J. A. Martens, J. Weitkamp and P.A. Jacobs) .... 427
Catalyseurs isolants et acidite - les acides paradoxaux
.....................................................
(Y. Trambouze) 437
IX
Studies in Surface Science and Catalysis
Volume 1 Preparation of Catalysts I. Scientific Bases for the Preparation of Heterogeneous
Catalysts. Proceedings of the First International Symposium held at the Solvay
Research Centre, Brussels, October 14-1 7, 1975
edited by B. Delrnon, P.A. Jacobs and G. Poncelet
Volume 2 The Control of the Reactivity of Solids. A Critical Survey of the Factors that In-
fluence the Reactivity of Solids, with Special Emphasis on the Control of the Chem-
ical Processes in Relation to Practical Applications
by V.V. Boldyrev, M. Bulens and B. Delmon
Volume 3 Preparation of Catalysts II. Scientific Bases for the Preparation of Heterogeneous
Catalysts. Proceedings of the Second International Symposium, Louvain-la-Neuve.
September 4-7, 1978
edited by B. Delmon, P. Grange, P. Jacobs and G. Poncelet
Volume 4 Growth and Properties of Metal Clusters. Applications to Catalysis and the Photo-
graphic Process. Proceedings of the 32nd International Meeting of the Soci6tte'de
Chirnie physique, Villeurbanne, September 24-28, 1979
edited by J. Bourdon
Volume 5 Catalysis by Zeolites. Proceedings of an International Symposium organized by the
lnstitut de Recherches sur la Catalyse - CNRS - Villeurbanne and sponsored by the
Centre National de la Recherche Scientifique, Ecully (Lyon), September 9-1 1,
1980
edited by B. Imelik, C. Naccache, Y. Ben Taarit, J.C. Vedrine, G. Coudurier and
H. Praliaud
Volume 6 Catalyst Deactivation. Proceedings of the International Symposium, Antwerp,
October 13-1 5,1980
edited by B. Delrnon and G.F. Froment
Volume 7 New Horizons in Catalysis. Proceedings of the 7th International Congress on
Catalysis, Tokyo, 30 June-4 July 1980
edited by T. Seiyama and K. Tanabe
Volume 8 Catalysis by Supported Complexes
by Yu.1. Yerrnakov, B.N. Kuznetsov and V.A. Zakharov
Volume 9 Physiaof Solid Surfaces. Proceedings of the Symposium held in Bechyfie, Czecho-
slovakia, September 29-October 3, 1980
edited by M. L&niEka
Volume 10 Adsorption at the Gas-Solid and Liquid-Solid Interface. Proceedings of an Inter-
national Symposium held in Aix-en-Provence, September 21 -23, 1981
edited by J. Rouquerol and K.S.W. Sing
Volume 11 Metal-Support and Metal-Additive Effects in Catalysis. Proceedings of an Interna-
tional Symposium organized by the lnstitut de Recherches sur la Catalyse - CNRS -
Villeurbanne and sponsored by the Centre National de la Recherche Scientifique,
Ecully (Lyon), September 14-16, 1982
edited by B. Imelik, C. Naccache, G. Coudurier, H. Praliaud, P. Meriaudeau,
P. Gallerot, G.A. Martin and J.C. Vedrine
Volume 12 Metal Microstructures in Zeolites. Preparation - Properties - Applications.
Proceedings of a Workshop, Bremen, September 22-24,1982
edited by P.A. Jacobs, N.I. Jaeger, P. Jiru and G. Schulz-Ekloff
Volume 13 Adsorption on Metal Surfaces. An Integrated Approach
edited by J. &nard
Volume 14 Vibrations at Surfaces. Proceedings of the Third International Conference, Asilomar,
California, U.S.A., 1-4S eptember 1982
edited by C.R. Brundle and H. Morawitz
Volume 15 Heterogeneous Catalytic Reactions Involving Molecular Oxygen
by G.I. Golodets
Volume 16 Preparation of Catalysts I II. Scientific Bases for the Preparation of Heterogeneous
Catalysts. Proceedings of the Third International Symposium, louvain-la-Neuve,
September 6-9, 1982
edited by G. Poncelet, P. Grange and P.A. Jacobs