Boranes and Metalloboranes: Structure, Bonding, and Reactivity

76 Pages·07.078 MB·English

by  Catherine E. Housecroft

BORANESAND
METALLOBORANES
Structurea,nR deB aocntdiivnigt y
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CATHERIEN.HE O USECROa.Ff.SP •eh .D.
felolfNo eww nhCaoml laenRgdoe y Saocli eR�tsye aFre!clho w
UniveCrhseimtLiyac ablo ra_.Ct aomnbensdge
ELLHIOSR WOOSDE RIIENIS N ORGACNHIECM ISTRY
SerieJ JEB.dU íRwGrE:DS eSp.a rolfmCchrietm Uinsitvrcoyrf.Ls eiitcye stcr
lnorcghacnmiiicss f 1laryo urdiisschiiipinnltg ois wnr nei gahnatdl psloa aky csry o ilmnea ny
arcoaorsr g,mompchtyasbliilcoíalcloa..ng dii ncdaulcs.ht ermiiaTslhit s sre yri.ids ec sv clopcd
trcoll ctchtt.v 'SCa raisopcuocsftt hssc u bfjrcocamtll le voeufln sd crgtreaadcuihanitttnehog e
uppchrr acokfc rtesc arch.
AlmoMn.dJ.. ShortM-ollievceudl es
Bcd:M.. T&. Nagypal, L ChemiosCfto rmypE lqeuxi libria
Bu rJg.1. -s.�. 1005i Sno luBtaisPoirnci: n coifCp hieemsli ncatle ractions
Bur�-s.�.J. Metlaolin Snsol ution
BurgJc.ss . lnorgSoalnuitcCi hoenm istry
C'arD<l.iJLn a..p• pcM r.tF&.. RasCt.oLn .
ChemiofstryO rgano-Ziracno-dnH iaufmnC ioummpo unds
ConstaEb.kC.. MetLallg lanntde ractions
Cnll.!iR.. J.Sq � PlanCaorm pleRxeesac:t Miecohna naindsH mosm ogeCnaetoaulsy sis
U,1rPr.iGs.o n. TiOnx iHdaen dhook
HartkFy..RB .u,r gCc.&ss A .l oockR.. M. SotuEtqiuoinl ihria ¡�
HayR.W. . BioinoCrhgeamniisct ry
HayR.W. . ReactiMoecnh anLo\fMm estC aolm plexes lffl
Housct.CT.nEf.l . Boranes anMde talloSbotrrauncBesto:un rdaein,nRd ge activity
Ltpp,mM.. FS.a.n gAc..rRS.. r ivaR�.lC&a. Pv oaw.cP r..PM .et aaln Mde taAlmliodieds
LMMaai�rrídl"Yndi>G·A.Ao. . c. Gt .. RedMoexc haMMniiailniisn GssnmorbS sroape gCCuucahhpetnee rrimm ociisc ssottprryyy ELLHIOSRP uWbOlOLi·CDsI hh MieIcrhTse EsDter
Mt.'GowJ;i&.nM ,d loAr.s. MolecVuollauirmCn esh emiasntBdri yo lo¡:y: Halsteadd iPvrioesfsi so:n
SRnoamRi,.tm&i ho EW..wi.d: l,;w aPr.d!i. LithaAinpiudptmC ls oie malpotnuidnoudnPdHssaii: rng tgDahSi lnltAatsdyrpnip TupdoeMocl nrextiisetiucndadrag ltet sysi ons NeYwo rCkJh Oi-cHhWN·BeI rsLitEse&·YbrTS a o OnroNen Sto
Wiilrru.al.p A .. O:i,;iZdoenG ee ix:hemistry

I 1#-
lntroduction [Ch.1 Sec. 1.4] Nomenclature 17
16
regpoullyahre odprra tot rnh� oefT.hi net r�oc�idoofn� antsit?im oetaf�al�m ents ThAem eicraCnh emicalh aoSsuo tcliitisean tceycdt ee dnp omencfloart ure
adadn se dwi rnennsooitno mlns y,t truurvcaaln abtuimtob nnod,m g esdncptnlasos boraanncthdis iss,c omnmlouys tehdr outghlheio tuetrl antourrge.1: 9 C6h8e,m .7,,
weUTo.ep rloebfrnasc wehdea nt temtprota� oitnnagtl hibezoe n gd.n it ineh broanse I 9N4u5m.b csrcihnegfm oseros rno etf h beo rcaangeae rgsei vine Fign7s .1..25.,1 ,7
antdh deierr ivaarfteui rvrteehsae fsroo mrnak sm tgh cam tafromgrve eitsg ttoain. 7..a3 dln 7 . 3.. 2
Toes truocfta mu orlee icsouf ltece onn firbmyme eda oosf a d irfatfcnio
technMioqscoutme m.o nXl�·ayyc,� rs tall�osug srcfadopth rhe� yn a ylsiosfs odl­i
stamtaet eHroiwaelgvsre.or w,sm mgt acbrlyes1 ntsoa ntle ssc selayen a,sa yesev ry
reseakrncoThwheser!r eiaffnoe rlee,mo ecrno tm po\uenniddt sst eooln ofemr o er
spectcorpcoit sechntihbqeeu neeasfir,ete ns o rmB�oruospn.o sssseneosjt su ton e,
buttw ioso,t o1peB0sa ,n11 dB ,w intohn -nzuelecrasorp ma,nt hd uthse e nsucial ree
suitfaobrl en uclreeasro snmpaaengccnteer tToihesi ccn otpryon. do aufnc 'teiixcoot
nude(uiss.'oe tm.hne igo thtehrta hnme o rceo mnmlooyb se1rHv,1e C3d,1 F9 a nd
31npu diet)ot hNeM Rs pectetreoirmasf uerrrt ahesofnom ra kitnhsgeut dyo f
boron-containianneg x ccipotrmiopocnst.ugp n eds
Finaitlflh syet, r uocftt hubero ersaa nrneeos v tehlew,ne s hoeuxlecpdtt heir
chetrym tisobe unusaunamdla,,y bunep,r edDiocetosan brele ueiqr!ea nmyo re
reasonsst ufdaoym ria ntge rial?
1.4N OMENCLATURE
Ustbeedl aorwse o rnceo mmtoenru mssei ndnm a inbgo rhodynri dce ompounds.
Toen amfeoa br o rhoynd riinddeit chnaeut mebosebf ro raonnhd dy rogena toam s:
Latipnr dgiixtv hesne u mboBefa r toamnsd Aar na bniuem biepnra rtehnessheosw s
thneu mboeHfra toFmosanr.i n ost,h ceh airisgnd eia tecdi npa renthe.se s
borane borohny dride
hydrtoebo ra borhoynd raindieo n
mono- one
d-i two
tri- three
tetra- for u
penta- five
hexa- six
hepta- seven
octa- eight
nona- nine
·<leca - ten
unideca- eleven
dodeca- twelve
trideca- thirteen
tetradeca- foeuernt
:J¡ ioosa- twteyn
,¡
ExampPleenst:a borane(9Bs)
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Pentabo1r1a)n e( BsH11
Octabo1r2a)n e( BsH12
Octahydrooctabora[BtHsesf(-2-)
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