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Gas Phase Uranyl Activation: Formation of A Uranium Nitrosyl Complex From Uranyl Azide PDF

5 Pages·2021·English
by  ['A']
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by ['A']| 2021| 5 pages| English

About Gas Phase Uranyl Activation: Formation of A Uranium Nitrosyl Complex From Uranyl Azide

The document discusses a study where collision induced dissociation of UO2(N3)Cl2- in a mass spectrometer resulted in the formation of UO(NO)Cl2-, indicating activation of the uranyl oxo bond. Density functional theory calculations predict the UO(NO)Cl2- complex has nonplanar Cs symmetry and a singlet ground state, with the side-on bonded NO moiety considered as NO3-, suggesting a U(VI) oxidation state. The observation provides a rare example of forming a uranium nitrido complex from uranyl.

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Author:['A']
Publication Year:2021
Pages:5
Language:English
Format:PDF
Price:FREE
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