Table Of Content2 I He 10 1 No 18 1 Ar 36 I Kr 54 I Xe 861 Rn Gl~
2 5 6 7 8
1H 9F 17CI 35Br 53J 85 At
8 3 a 16 9 S 3410 Se 5211 Te 8412 Po 71 Lu 0371 Lr I
1
7 4 N 1516 P 3317 As 5118 Sb :~ 19 70 Vb 10271 No(?)
6 14 C ~f15 3245 Ge 5°46 Sn 8247 Pb 69 Tm 10171 Md
ern II I I 13 35 36 37 38 1 7
n-Systemnumm , I , i ! I , I I I 5 I B I I 13i AI 60 30 32 31 Zn Ga 4961 48 33 Cd In 62 81 80 34 Hg TI 67 68 Ho Er 991001 71 7Es Fm
mit Gmeli ! I I I I , , I I ! I I I I i I 29 ~~ 57 Cu 4647 65 Ag Pd 7879 68 Au Pt 65 66 Tb Oy 979871 Bk Cf
e
ement 2758 Co 4564 Rh 77 67 Ir 64 Gd 9671 Cm
El
er 59 63 66 71
m d 26 Fe 44 Ru 76 as 63 Eu 95Am
ensysto I 25 56 Mn 4369 Te 7570 Re 62 Sm 9471 Pu
d
Perio i I I I ! I 2448 52 Cr 49 4253 Mo 7450 54 W 71 61 Pm 9371 55 Np
23V 41Nb 73Ta 105 60 Nd 92U
~~41 4042 Zr 7243 Hf 10471 59 Pr 9151 Pa
21 39 Se 3939 V 57** La 39 89*** Ac 40 58 Co 9044 Th
26 27 28 29 30 31 e 9
4 Be 12Mg 20Ca 38Sr 56Ba 88Ra n id3 de
I 2 H 3 Li 20 1121 Na 1922 K 3724 Rb 5525 Cs 87 Fr *Lantha **Aetini
* *
' '
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Gmelin Handbuch der Anorganischen Chemie
Achte v611ig neu bearbeitete Auflage
Main Series, 8th Edition
Volumes published on "Transuranium Elements"
Bisher erschienene Bande zu "Transurane"
Transurane A 1. I (Erg.-Werk Band 7 a)
Die Elemente - 1973
Transurane A 1. II (Erg.-Werk Band 7 b)
Die Elemente - 1974
Transurane A 2 (Erg.-Werk Band 8)
Die Elemente - 1973
Transurane B 1 (Erg.-Werk Band 31)
Die Metalle - 1976
Transurane B 2 (Erg.-Werk Band 38)
Binare Legierungssysteme 1 - 1976
Transurane B 3 (Erg.-Werk Band 39)
Binare Legierungssysteme 2 - 1977
Transurane C (Erg.-Werk Band 4)
Die Verbindungen - 1972
Transurane D 1 (Erg.-Werk Band 20)
Chemie in Losung - 1975
Transurane D 2 (Erg.-Werk Band 21)
Chemie in Losung - 1975
Transuranium Elements Index
Alphabetical Subject and Substance Index - 1979
Gmelin Handbuch
der Anorganischen Chemie
BEGRONDET VON Leopold Gmelin
Achte vollig neu bearbeitete Auflage
ACHTE AUFLAGE begonnen im Auftrage der Deutschen Chemischen Gesellschaft
von R. J. Meyer
E. H. E. Pietsch und A. Kotowski
fortgefiihrt von
Margot Becke-Goehring
HERAUSGEGEBEN VOM Gmelin-Institut fur Anorganische Chemie
der Max-Planck-Gesellschaft zur Forderung der Wissenschaften
Springer-Verlag Berlin Heidelberg GmbH 1979
Gmelin-Institut fUr Anorganische Chemie
der Max-Planck-Gesellschaft zur Forderung der Wissenschaften
KURATORIUM (ADVISORY BOARD)
Dr. J. Schaafhausen, Vorsitzender (Hoechst AG, Frankfurt/Main-Hochst), Dr. G. Breil (Ruhrchemie
AG, Oberhausen-Holten), Prof. Dr. R. Brill (Lenggries), Dr. G. Broja (Bayer AG, Leverkusen), Prof.
H. J. EmelEJus, Ph. D., D. Sc., FRS (University of Cambridge), Prof. Dr. G. Fritz (Universitat Karlsruhe),
Prof. Dr. Dr. E. h. O. Glemser (Universitat Gottingen), Prof. Dr. Dr. E. h. O. Haxel (Heidelberg),
Prof. Dr. Dr. h. c. H. Hellmann (Chemische Werke Huls AG, Marl), Prof. Dr. R. Hoppe (Universitat
GieBen), Prof. Dr. R. Lust (Prasidentder Max-Planck-Gesellschaft, Munchen), Prof. Dr. E. L. Muetterties
(University of California, Berkeley, California), Prof. Dr. H. Schafer (Universitat Munster), Prof. Dr. Dr.
h.c. mult. G. Wilke (Max-Planck-Institut fUr Kohlenforschung, Mulheim/Ruhr)
DIREKTOR STELLVERTRETEN DER DIREKTOR
Prof. Dr. Dr. E. h. Margot Becke Dr. W. Lippert
HAUPTREDAKTEURE (EDITORS IN CHIEF)
Dr. K.-C. Buschbeck, Standiger Hauptredakteur
Dr. H. Bergmann, Dr. H. Bitterer, Dr. H. Katscher, Dr. R. Keim, DipJ.-lng. G. Kirschstein, DipJ.-Phys.
D. Koschel, Dr. U. Kruerke, Dr. H. K. Kugler, Dr. E. Schleitzer-Rust, Dr. A. Slawisch, Dr. K. Swars,
Dr. R. Warncke
MITARBEITER (STAFF)
Z. Amerl, D. Barthel, Dr. N. Baumann, J. Baumhauer, Dr. K. Beeker, Dr. W. Behrendt, Dr. L. Berg,
DipJ.-Chem. E. Best, M. Brandes, E. Brettschneider, E. Cloos, DipJ.-Phys. G. Czack, J. Deim, L. Demmel,
DipJ.-Chem. H. Demmer, R. Dombrowsky, R. Dowideit, DipJ.-Chem. A. Drechsler, DipJ.-Chem.
M. DroBmar, J. Eifler, M. Engels, Dr. H.-J. Fachmann, J. Fischer, Dr. R. Frobose, J. Fussel, DipJ.-lng.
N. Gagel, DipJ.-Chem. H. Gedschold, E. Gerhardt, Dr. U. W. Gerwarth, DipJ.-Phys. D. Gras, Dr. V. Haase,
H. Hartwig, B. Heibel, DipJ.-Min. H. Hein, G. Heinrich-Sterzel, H.-P. Hente, H. W. Herold, U. Hettwer,
Dr. J. Hinz, Dr. W. Hoffmann, DipJ.-Chem. K. Holzapfel, E.-M. Kaiser, DipJ.-Chem. W. Karl, H.-G.
Karrenberg, DipJ.-Phys. H. Keller-Rudek, DipJ.-Phys. E. Koch, Dr. E. Koch, DipJ.-Chem. K. Koeber,
H. Koppe, DipJ.-Chem. H. Kottelwesch, R. Kolb, E. Kranz, L. Krause, DipJ.-Chem. J. Kreuzbichler,
Dr. A. Kubny, Dr. N. Kuhn, Dr. P. Kuhn, M. Langer, M.-L. Lenz, Dr. A. Leonard, DipJ.-Chem. H. List,
H. Mathis, K. Mayer, E. Meinhard, Dr. P. Merlet, K. Meyer, M. Michel, Dr. A. Mirtsching, K. Noring,
C. Pielenz, E. PreiBer, J. Rangnow, DipJ.-Phys. H.-J. Richter-Ditten, DipJ.-Chem. H. Rieger, E. Rudolph,
G. Rudolph, DipJ.-Chem. S. Ruprecht, DipJ.-Chem. D. Schneider, Dr. F. Schroder, DipJ.-Min. P. Schu
bert, DipJ.-lng. H. Somer, E. Sommer, Dr. P. StieB, M. Teichmann, Dr. W. Topper, Dr. B. V. Tschirschnitz
Geibler, DipJ.-lng. H. Vanecek, DipJ.-Chem. P. Velie, DipJ.-lng. U. Vetter, DipJ.-Phys. J. Wagner,
R. Wagner, DipJ.-Chem. S. Waschk, Dr. G. Weinberger, Dr. H. Wendt, H. Wiegand, C. Wolff, K. Wolff,
Dr. A. Zelle, U. Ziegler
FREIE MITARBEITER (CORRESPONDENT MEMBERS OF THE SCIENTIFIC STAFF)
Dr. J. Kubach, Dr. J. F. Rounsaville, Dr. K. Rumpf, Dr. U. Trobisch
AUSWARTIGE WISSENSCHAFTLICHE MITGLIEDER Prof. Dr. Hans Bock
(CORRESPONDENT MEMBERS OF THE INSTITUTE) Prof. Dr. Dr. Alois Haas, Sc. D. (Cantab.)
Prof. Dr. Dr. h. C. Erich Pietsch
Gmelin Handbuch
der Anorganischen Chemie
Achte v611ig neu bearbeitete Auflage
Main Series. 8th Edition
Np, Pu ...
Transuranium Elements
INDEX
Alphabetical Index of Subjects and Substances
AUTHOR Ursula Hettwer
(BEARBEITER)
Beratende Mitwirkung: Gunter Koch. Kernforschungszentrum
Karlsruhe
Springer-Verlag Berlin Heidelberg GmbH 1979
Table of Contents
Page
Comments on the Index .................... " 1
Alphabetical Index of Subjects and Substances. . .. 2
List of Abbreviations for Extractants, Diluents,
and Chelating Agents . . . . . . . . . . . . . . . . . . .. 241
Die vierte bis siebente Auflage dieses Werkes erschien im Verlag
von Carl Winter's Universitiitsbuchhandlung in Heidelberg
Library of Congress Catalog Card Number: Agr 25-1383
ISBN 978-3-662-05676-9 ISBN 978-3-862-05674-5 (eBook)
00110.10071978-3-882-05874-5
Die Wiedergabe von Gebrauchsnamen. Handelsnamen. Warenbezeichnungen usw. im Gmelin Handbuch berechtigt auch
ohne besondere Kennzeichnung nicht zu der Annahme. daB solche Namen im Sinne der Warenzeichen- und Marken
schutz-Gesetzgebung als frei zu betrachten wiren und daher von jedermann benutzt werden diirften.
Das Werk ist urheberrechtlich geschiitzt. Die dadurch begriindeten Rechte. insbesondere die dar Obersetzung. des Nach
druckes. der Entnahma von Abbildungen. dar Funksandung. dar Wiedergabe auf photomechanischem oder iihnlichem
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©
by Springer·Veriag Berlin Heidelberg 1979
Originally published by Springer-Verlag Berlin Heidelberg New York in 1979
Softcover reprint of the hardcover 8th edHion 1979
Comments on the Index
This index includes in alphabetical order entries for subjects and substances described in the
9 volumes A 1, I; A 1, II; A 2; B 1; B 2; B 3; C; D 1; and D 2 of "Transuranium Elements".
Corresponding volume numbers in the New Supplement Series are 4, 7 a, 7 b, 8, 20, 21, 31, 38,
and 39. The index has entries both for general subjects on all transuranium elements and for subjects
on a specific element or its alloys, compounds, or isotopes.
The choice of topics treated in "Transuranium Elements" is broader than that usually in a
Gmelin volume. In addition to topics such as occurrence, preparation, physical properties, and
chemical behavior, there is extensive material on applications, recovery, reprocessing, health physics,
etc. To help the user find what he seeks, a topic is frequently listed under several entries, which are
of varying degrees of generality. Further, the material under a broad main entry is broken down into
several levels of subheadings. There are also many cross references. These efforts are intended to
aid both the user seeking specific information and the user seeking general information.
For example, there are main entries for "Sulfex process" and" Purex process". But these terms
can also be found as subheadings under the main entry" Nuclear reactor fuel reprocessing ", along
with the related subheadings "by solvent extraction" and "dissolution of fuel core". Furthermore,
the same material can be located under the main entry "Plutonium" through the subheadings
"recovery" and" separation ". A second example is the material on the biological effects of plutonium.
The main entry is "Health physics ", but much of the material can be located under entries like
"Plutonium, handling" or "Plutonium isotopes, radiation biology".
If the user seeks information on a specific element, he should go directly to that element. The
material is arranged in the same order for each element. For the example plutonium:
Plutonium
Plutonium alloys
Plutonium compounds
Plutonium ions
Plutonium isotopes
Plutonium oxo ions
0.,
A page is listed under the "isotope" heading only if specific isotopes are mentioned in the text
that page.
After each entry the pertinent volume and pages are given. For example, A 1, II 177 refers to
page 177 of "Transuranium Elements" A 1, II. The most important pages are given in boldface type.
A "List of Abbreviations for Extractants, Diluents, and Chelating Agents" that are commonly
used in nuclear technology and radiochemistry is given in the appendix starting on page 241.
However, trivial names and trade names have been omitted from the list.
Gmelin Handbuch
2 Absorption spectra Transuranium Elements
Absorption spectra
crystal A2 50/1,54/62,64/8,71/2,
74
gas phase ....................•................. A2 55/7,67,72,74
of dipositive ions ................................ . A 2 49/51
of oxidation states V, VI, and VII .................... . A2 49/50,69/76
of tetravalent ions ............................... . A2 49/50,63/9
of tripositive ions ................................ . A 2 49/63
solution ....................................... . A 2 51/5, 57, 59/64, 66/76
02 206/7,227, 229, 347,
356/8
Actinide concept, see Actinide theory
Actinide contraction A2 4/5
Actinide group A 2 2
Actinides, see Americium, Berkelium, Californium, Curium,
Einsteinium, Fermium, Lawrencium, Mendelevium, Neptunium,
Nobelium, and Plutonium
Actinide theory A 1,1 6/7
A 2 2,11
Actinyl, see Americium oxo ions, Neptunium oxo ions, and
Plutonium oxo ions
Airox process A 1,11 248
Alloys, see Americium alloys, Berkelium alloys, Californium alloys,
Curium alloys, Einsteinium alloys, Fermium alloys, Mendelevium
alloys, Neptunium alloys, Nobelium alloys, and Plutonium
alloys
Alpha group identification A 1,1 85/95
Alpha particle bombardment, see Charged particle reactions
Alpha particle decay, see Decay, alpha decay
Alpha radiation, see Decay, alpha decay
Amalgam process A 1,11 241/2
Americium
(see also Americium ions, Americium isotopes)
alloys, see Americium alloys
analysis
- detection and determination
- by calorimetry ............................. . A 2 169
- by complexometric methods .................. . A 2 165
by coulometry ............................. . A 2 165
by emission spectrography ................... . A 2 165
by gravimetric methods ...................... . A 2 164/5
by mass spectrometry ....................... . A 2 166
by radiometric methods ...................... . A 2 167/9,185/6
by spectrophotometry ....................... . A 2 165/6
by X-ray fluorescence spectrometry ............ . A 2 166
in biological materials ....................... . A 2 185/6
Index Americium, complex chemistry 3
Americium
analysis
- detection and determination (cont.)
- in Pu-AI alloys ............................ . A 2 166
- in PU02 .................................. . A 2 165/6
- in radioactive fallout ........................ . A 1, II 355/7
- in vivo ................................... . A2 345
- of isotope composition ...................... . A 2 166
- of oxidation states .......................... . A 2 166
- isotope analysis, see Americium isotopes, analysis
- separation
by co precipitation .......................... . A 2 170/3, 185/6
by electrophoresis .......................... . A 2 172/3
01 24/6
by ion exchange ........................... . A 2 170/2, 185/6
by solvent extraction ........................ . A 2 170/3, 185/6
- chromatography ......................... . A 2 171/3
02 291
- from biological materials ..................... . A 2 185/6
- from lanthanides ........................... . A 2 171/2
- from plutonium ............................ . A 2 170
- from promethium .......................... . 02 291
- from radioactive fallout ...................... . A 1, 11355/6
- from transcurium elements A 2 171
- specific A 2 172/3
atomic energy levels
(see also Americium ions, atomic energy levels)
- optical ..................................... . A2 42/3
- X-ray ...................................... . A2 80/1
atomic mass A 1, I 128
atomic radius A2 5
B1 63
atomic volume B 1 63
atomic weight A 1, I 2
boiling point B 1 64
complex chemistry
(see also Americium compounds)
- in aqueous solutions
- hydration ................................. . 01 132/3
- hydrolysis ................................ . 01 133/6
- with anions of monoprotonic inorganic acids 01 138/9,141/5
- with anions of multiprotonic inorganic acids 01 147/9
- with carboxylic acids ....................... . 01 151/9
- with chelating ligands ....................... . 01 151/69
- with hydroxycarboxylic acids ................. . 01 151/4,157,159
- in nonaqueous solutions
- with amines and ammonium compounds ........ . 02 331/3,337
- with cupferron and neocupferron .............. . 02 323/4
- with ~-diketones ........................... . 02 239/47
- with hydroxamic acids ...................... . 02 323
- with hydroxylamine derivatives ................ . 02 321/4
1·
